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Alkene and Thioether Oxidations with H2O2 over Ti-Containing Mesoporous Mesophase Catalysts Научная публикация

Конференция Physical Methods for Catalytic Research at the Molecular Level: International memorial K.I. Zamaraev conference
28 июн. - 2 июл. 1999 , Novosibirsk
Журнал Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169
Вых. Данные Год: 2000, Том: 158, Номер: 1, Страницы: 417-421 Страниц : 5 DOI: 10.1016/S1381-1169(00)00116-3
Ключевые слова Mesoporous mesophase catalysts, Oxidation, Titanium
Авторы Kholdeeva Oxana A. 1 , Derevyankin Alexander Yu. 1 , Shmakov Alexander N. 1 , Trukhan Nataliya N. 2 , Paukshtis Eugenii A. 1 , Tuel Alain 3 , Romannikov Vyacheslav N. 1
Организации
1 Boreskov Institute of Catalysis, Russian Academy of Sciences, Prospect Lavrentieva 5, Novosibirsk, 630090 Russia
2 Novosibirsk State University, Novosibirsk 630090, Russia
3 Institut de Recherches sur la Catalyse, C.N.R.S., 2 Avenue Albert Einstein, 69626 Villeurbanne Cedex, France

Информация о финансировании (2)

1 Российский фонд фундаментальных исследований 98-03-32390
2 Российский фонд фундаментальных исследований 98-03-22060

Реферат: Well-organized Ti-containing mesoporous mesophase materials (Ti-MMM) have been synthesized by hydrothermal synthesis using C16H33N(CH3)3Br and characterized by elemental analysis, IR, DRS-UV, XRD, and N2 adsorption. Catalytic properties of these materials in alkene and thioether oxidations with aqueous H2O2 in CH3CN have been studied and compared with those of the Ti-containing hexagonal mesoporous silica (Ti-HMS). The Ti-MMM catalysts with the Si/Ti atomic ratio varying in the range of 49–124 showed the highest catalytic activities in alkene oxidation. Both the structure of a silicate matrix and a degree of isolation of titanium ions in it are crucial factors determining catalytic activity of Ti-MMM. For thioether oxidation, the structural perfection of Ti-MMM catalysts is less important. No leaching of titanium ions occurs during both reactions. The oxidation process proved to be truly heterogeneous.
Библиографическая ссылка: Kholdeeva O.A. , Derevyankin A.Y. , Shmakov A.N. , Trukhan N.N. , Paukshtis E.A. , Tuel A. , Romannikov V.N.
Alkene and Thioether Oxidations with H2O2 over Ti-Containing Mesoporous Mesophase Catalysts
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.417-421. DOI: 10.1016/S1381-1169(00)00116-3 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована online: 18 июл. 2000 г.
Опубликована в печати: 8 сент. 2000 г.
Идентификаторы БД:
Web of science: WOS:000089201200059
Scopus: 2-s2.0-0034623039
РИНЦ: 13360468
Chemical Abstracts: 2000:498720
Chemical Abstracts (print): 133:296115
OpenAlex: W1970476050
Цитирование в БД:
БД Цитирований
Web of science 43
Scopus 46
РИНЦ 45
OpenAlex 38
Альметрики: