Direct ESR Detection of S=3/2 States for Nitrosyl Iron Complexes in FeZSM-5 Zeolites Full article
| Journal |
Chemical Physics Letters
ISSN: 0009-2614 , E-ISSN: 1873-4448 |
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| Output data | Year: 2001, Volume: 333, Number: 1-2, Pages: 41-44 Pages count : 4 DOI: 10.1016/S0009-2614(00)01357-9 | ||||
| Tags | NITRIC-OXIDE; Fe-ZSM-5 ZEOLITES; NO; OXIDATION; BENZENE; SPECTROSCOPY; CATALYSTS; MECHANISM; PROTEINS; MIXTURES | ||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 00-03-32441 |
| 2 | Swedish Research Council | |
| 3 | Royal Swedish Academy of Sciences |
Abstract:
The formation of paramagnetic complexes between Fe2+ ions and NO molecules with total spin S=3/2 has been observed in FeZSM-5 zeolites. These complexes exhibit a typical ESR signal with a component at g=4.0 and are spectroscopically similar to those observed in iron-containing enzymes. Such spin states of Fe ions have not been reported for heterogeneous catalysts. The application of NO as a spin probe for investigation of the state of low-valence Fe ions in zeolite matrices is discussed.
Cite:
Volodin A.M.
, Dubkov K.A.
, Lund A.
Direct ESR Detection of S=3/2 States for Nitrosyl Iron Complexes in FeZSM-5 Zeolites
Chemical Physics Letters. 2001. V.333. N1-2. P.41-44. DOI: 10.1016/S0009-2614(00)01357-9 WOS Scopus РИНЦ ANCAN OpenAlex
Direct ESR Detection of S=3/2 States for Nitrosyl Iron Complexes in FeZSM-5 Zeolites
Chemical Physics Letters. 2001. V.333. N1-2. P.41-44. DOI: 10.1016/S0009-2614(00)01357-9 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 16, 2000 |
| Published print: | Jan 5, 2001 |
| Published online: | Jul 11, 2001 |
Identifiers:
| Web of science: | WOS:000166508000008 |
| Scopus: | 2-s2.0-0002183508 |
| Elibrary: | 13386002 |
| Chemical Abstracts: | 2001:107065 |
| Chemical Abstracts (print): | 134:201884 |
| OpenAlex: | W1999749527 |