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Sorption-Enhanced Reforming of Bioethanol in Dual Fixed Bed Reactor for Continuous Hydrogen Production Full article

Conference Euro-mediterranean Hydrogen Technologies Conference (EmHyTeC2014)
09-12 Dec 2014 , Taormina
Journal International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487
Output data Year: 2015, Volume: 40, Number: 42, Pages: 14436-14444 Pages count : 9 DOI: 10.1016/j.ijhydene.2015.06.029
Tags Adsorption, Carbon dioxide sorbent, High temperature pressure swing, Hydrogen production, Sorption-enhanced reforming
Authors Lysikov Anton 1,2,3,4 , Derevschikov Vladimir 1,2,3 , Okunev Alexey 1,2
Affiliations
1 Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk, 630090, Russia
2 Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russia
3 Research and Education Centre, NSU, Pirogova str. 2, Novosibirsk, 630090, Russia
4 Strategic Development Program “MRA-199”, Skolkovo Institute of Science and Technology, Novaya Street 100, Moscow, 143025, Russia

Funding (3)

1 Russian Foundation for Basic Research 14-03-31731
2 Skolkovo Institute of Science and Technology 199-MRA
3 Council for Grants of the President of the Russian Federation СП-3164.2015.1

Abstract: The sorption enhanced reforming (SER) of ethanol over an admixture of CaO sorbent and Ni reforming catalyst has been experimentally studied in a periodically operated dual fixed bed reactor. The optimal parameters for SER process were calculated from thermodynamic data. The experiment was carried out in cyclic mode; temperature swing adsorption and pressure swing adsorption (PSA) modes were used for periodic sorbent regeneration. It was shown that the continuous hydrogen production and the purity of hydrogen during the sorption-catalytic ethanol reforming maintained at the constant level and were 50 L/min and 97e99 vol.% respectively. The dual fixed bed SER reactor worked fine during 2 months on stream and more than 250 cycles. Both the sorbent and the catalyst maintained the sufficient activity during experiment. The obtained results suggest that sorption enhanced reforming may be a perspective approach for hydrogen production in fuel cell powered cogeneration systems.
Cite: Lysikov A. , Derevschikov V. , Okunev A.
Sorption-Enhanced Reforming of Bioethanol in Dual Fixed Bed Reactor for Continuous Hydrogen Production
International Journal of Hydrogen Energy. 2015. V.40. N42. P.14436-14444. DOI: 10.1016/j.ijhydene.2015.06.029 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Feb 26, 2015
Accepted: Jun 5, 2015
Published online: Jun 29, 2015
Published print: Nov 1, 2015
Identifiers:
Web of science: WOS:000364256300003
Scopus: 2-s2.0-84948710231
Elibrary: 25168994
Chemical Abstracts: 2015:1077981
Chemical Abstracts (print): 163:506949
OpenAlex: W1939669115
Citing:
DB Citing
Web of science 10
Scopus 13
Elibrary 12
OpenAlex 13
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