Synthesis and Structural Features of Nanostructured Cuprous Chloride with High Catalytic Activity | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis and Structural Features of Nanostructured Cuprous Chloride with High Catalytic Activity Full article

Journal

Silicon
ISSN: 1876-990X , E-ISSN: 1876-9918

Output data

Year: 2015, Volume: 7, Number: 2, Pages: 79-87 Pages count : 8 DOI: 10.1007/s12633-014-9272-5

Tags

Copper catalyst, Cuprous chloride, Direct synthesis, Nanoparticles, Nanostructured, Silicon, Trialkoxysilanes, Triethoxysilane

Authors

Adonin Nicolay Yu. ¹ , Prikhodʹko Sergey A. ¹ , Shabalin Anton Yu. ¹ , Prosvirin Igor P. ¹ , Zaikovskii Vladimir I. ^1,2 , Kochubey Dmitry I. ¹ , Zyuzin Dmitry A. ¹ , Parmon Valentin N. ¹ , Monin Evgeny A. ³ , Bykova Irina A. ³ , Martynov Petr O. ³ , Rusakov Sergey L. ³ , Storozhenko Pavel A. ³

Affiliations

1	G.K. Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	The State Scientific Center of the Russian Federation State Research Institute for Chemistry and Technology of Organoelement Compounds, Moscow, Russia

Funding (1)

Russian Foundation for Basic Research

13-03-12246

A method for nanostructured cuprous chloride preparation by reductive thermolysis of a CuCl2⋅2H2O and Cu(OH)2 mixture in glycerol has been developed. The resultant CuCl was characterized with infrared spectroscopy, X-ray photoelectron spectroscopy, EXAFS spectroscopy, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The prepared samples of CuCl demonstrated high catalytic activity in the “direct synthesis” of triethoxysilane.

Adonin N.Y. , Prikhodʹko S.A. , Shabalin A.Y. , Prosvirin I.P. , Zaikovskii V.I. , Kochubey D.I. , Zyuzin D.A. , Parmon V.N. , Monin E.A. , Bykova I.A. , Martynov P.O. , Rusakov S.L. , Storozhenko P.A.
Synthesis and Structural Features of Nanostructured Cuprous Chloride with High Catalytic Activity
Silicon. 2015. V.7. N2. P.79-87. DOI: 10.1007/s12633-014-9272-5 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Apr 28, 2014
Accepted:	Aug 26, 2014
Published online:	Feb 28, 2015
Published print:	Apr 1, 2015

Web of science:	WOS:000354546500003
Scopus:	2-s2.0-84941743113
Elibrary:	24949524
Chemical Abstracts:	2015:449081
Chemical Abstracts (print):	163:339803
OpenAlex:	W2018704552

DB	Citing
Web of science	5
Scopus	5
Elibrary	6
OpenAlex	5