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Low-Temperature Decomposition of Ammonia Borane in the Presence of Titania Full article

Journal Inorganic Materials
ISSN: 0020-1685 , E-ISSN: 1608-3172
Output data Year: 2011, Volume: 47, Number: 10, Pages: 1101-1106 Pages count : 6 DOI: 10.1134/S0020168511100116
Tags THERMAL-DECOMPOSITION; HYDROGEN RELEASE; BORIC-ACID; SPECTRA; DEHYDROGENATION; CATALYSTS; COMPONENT; GLASSES; SYSTEM
Authors Komova O.V. 1 , Simagina V.I. 1 , Odegova G.V. 1 , Chesalov Y.A. 1 , Netskina O.V. 1 , Ozerova A.M. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090 Russia

Funding (1)

1 Russian Foundation for Basic Research 09-08-00505

Abstract: In the presence of anatase, the thermal decomposition of ammonia borane (AB) begins at a lower temperature, which enables AB dehydrogenation at a temperature as low as 80°C. The reduction in the AB decomposition temperature depends on the AB content of the mixture. In situ IR spectroscopy data demonstrate that, in the presence of TiO2, the structural destabilization of AB occurs during heating and is accompanied by the formation of an oxygen-containing boron phase and partial reduction of the titania, which is supported by diffuse reflectance spectroscopy data.
Cite: Komova O.V. , Simagina V.I. , Odegova G.V. , Chesalov Y.A. , Netskina O.V. , Ozerova A.M.
Low-Temperature Decomposition of Ammonia Borane in the Presence of Titania
Inorganic Materials. 2011. V.47. N10. P.1101-1106. DOI: 10.1134/S0020168511100116 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Комова О.В. , Симагина В.И. , Одегова Г.В. , Чесалов Ю.А. , Нецкина О.В. , Озерова А.М.
Низкотемпературное разложение амминборана в присутствии диоксида титана
Неорганические материалы. 2011. Т.47. №10. С.1211-1216. РИНЦ
Dates:
Submitted: Dec 27, 2010
Accepted: Mar 18, 2011
Published online: Sep 17, 2011
Published print: Oct 1, 2011
Identifiers:
Web of science: WOS:000296739200010
Scopus: 2-s2.0-80053950545
Elibrary: 18008971
Chemical Abstracts: 2011:1168752
Chemical Abstracts (print): 155:656438
OpenAlex: W2094466979
Citing:
DB Citing
Web of science 13
Scopus 14
Elibrary 13
OpenAlex 13
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