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Low Temperature Hydrogen Purification from CO for Fuel Cell Application over Copper–Ceria Catalysts Supported on Different Oxides Full article

Journal International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487
Output data Year: 2011, Volume: 36, Number: 1, Pages: 1271-1275 Pages count : 5 DOI: 10.1016/j.ijhydene.2010.06.126
Tags Ceria, Copper, PROX, XPS, XRD, Zirconia
Authors Kosmambetova G.R. 1 , Moroz E.M. 1,2 , Guralsky A.V. 1 , Pakharukova V.P. 1,2 , Boronin A.I. 1,2 , Ivashchenko T.S. 1 , Gritsenko V.I. 1 , Strizhak P.E. 1
Affiliations
1 Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Pr. Nauki, 31, Kiev 03039, Ukraine
2 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva, 5, Novosibirsk 630090, Russia

Funding (1)

1 Russian Foundation for Basic Research 09-03-90424

Abstract: The CuO–CeO2–MeOx (Me = Zr, Ti, Mn, Al; x = 1.5–2) solids were tested in the preferential CO oxidation reaction in hydrogen-rich gas mixtures (PROX). We study an effect of a support (MeOx) the CO conversion and selectivity in the PROX reaction showing that monoclinic zirconia (m-zirconia) with low surface area is the most effective support. The optimal catalyst composition was determined by varying copper and ceria loadings over m-zirconia. XRD and XPS studies indicate that a good catalytic performance of m-zirconia supported copper–ceria catalysts may be attributed to the presence of dispersed Cu-containing species that interact with CeO2 and ZrO2.
Cite: Kosmambetova G.R. , Moroz E.M. , Guralsky A.V. , Pakharukova V.P. , Boronin A.I. , Ivashchenko T.S. , Gritsenko V.I. , Strizhak P.E.
Low Temperature Hydrogen Purification from CO for Fuel Cell Application over Copper–Ceria Catalysts Supported on Different Oxides
International Journal of Hydrogen Energy. 2011. V.36. N1. P.1271-1275. DOI: 10.1016/j.ijhydene.2010.06.126 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jun 25, 2010
Accepted: Jun 25, 2010
Published online: Aug 19, 2010
Published print: Jan 1, 2011
Identifiers:
Web of science: WOS:000288102700147
Scopus: 2-s2.0-79251627442
Elibrary: 23957315
Chemical Abstracts: 2011:124969
Chemical Abstracts (print): 154:314328
OpenAlex: W2016222053
Citing:
DB Citing
Web of science 17
Scopus 18
Elibrary 19
OpenAlex 20
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