Sciact
  • EN
  • RU

Design and Testing of Structured Catalysts for Internal Reforming of CH4 in Intermediate Temperature Solid Oxide Fuel Cells (IT SOFC) Full article

Conference Electrochemical Society's 219th Meeting, 12 International Symposium on Solid Oxide Fuel Cells
01-06 May 2011 , Montreal
Journal ECS Transactions
ISSN: 1938-5862 , E-ISSN: 1938-6737
Output data Year: 2011, Volume: 35, Number: 1, Pages: 2771-2780 Pages count : 10 DOI: 10.1149/1.3570276
Tags METHANE; PERFORMANCE; ANODES
Authors Smirnova A.L. 1 , Sadykov V.A. 2,3 , Mezentseva N.V. 2 , Bunina R.V. 2 , Pelipenko V.V. 2 , Alikina G.M. 2 , Krieger T.A. 2 , Bobrova L.N. 2 , Smorygo O. 4 , van Berkel F. 5 , Rietveld B. 5
Affiliations
1 Eastern Connecticut State University, Willimantic, CT, USA
2 Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia
3 Novosibirsk State University, Novosibirsk, 630090, Russia
4 Powder Metallurgy Institute, Minsk, 220005, Belarus
5 Energy Research Center of the Netherlands, Petten, 1755LE, The Netherlands

Funding (5)

1 Russian Foundation for Basic Research 09-03-12317
2 Siberian Branch of the Russian Academy of Sciences 57
3 European Commission 20089 FP6-2004-ENERGY-3 SOFC600
4 Президиум РАН 27
5 North Atlantic Treaty Organization SfP-980878

Abstract: Procedures for the synthesis of nanocomposite anode materials comprised of Ni-YSZ promoted by doped Ce-Zr-O fluorite-like or La-Pr-Mn-Cr-O perovskite-like oxides and Pt/Ru were elaborated. Their composition, structure, reactivity, and catalytic properties in CH4 steam reforming were characterized using various techniques, such as SEM, TEM, EDX, TPR, and I-V testing in SOFC conditions. The optimized nanocomposites supported on compressed foam Ni-Al substrates demonstrated high and stable performance at H2O:CH4=1:2 ratio without coking or sintering. For the SOFC testing, the planar catalytic substrates with the surface area of 5x5 cm2 have been used. The demonstrated SOFC performance in the internal CH4 reforming mode was close to the performace obtained with the humidified hydrogen. The achieved power density was up to 300-800 mW/cm2 at 600-800 oC meeting the targets of the area specific resistance, fuel effficiency, and power density.
Cite: Smirnova A.L. , Sadykov V.A. , Mezentseva N.V. , Bunina R.V. , Pelipenko V.V. , Alikina G.M. , Krieger T.A. , Bobrova L.N. , Smorygo O. , van Berkel F. , Rietveld B.
Design and Testing of Structured Catalysts for Internal Reforming of CH4 in Intermediate Temperature Solid Oxide Fuel Cells (IT SOFC)
ECS Transactions. 2011. V.35. N1. P.2771-2780. DOI: 10.1149/1.3570276 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Dec 16, 2019
Identifiers:
Web of science: WOS:000300770105029
Scopus: 2-s2.0-84856875640
Elibrary: 18035067
Chemical Abstracts: 2011:902957
Chemical Abstracts (print): 156:207745
OpenAlex: W2487572762
Citing:
DB Citing
Web of science 9
Scopus 12
Elibrary 9
OpenAlex 10
Altmetrics: