Pyrolysis of Liquid Hexadecane with Selective Microwave Heating of the Catalyst Full article
| Journal |
Theoretical and Experimental Chemistry
ISSN: 0040-5760 , E-ISSN: 1573-935X |
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| Output data | Year: 2011, Volume: 46, Number: 6, Pages: 384-392 Pages count : 9 DOI: 10.1007/s11237-011-9169-y | ||||||
| Tags | α-olefins, hexadecane, microwave, pyrolysis | ||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Siberian Branch of the Russian Academy of Sciences | 5 |
| 2 | Президиум РАН | 19.2 |
| 3 | Council for Grants of the President of the Russian Federation | НШ-3156.2010.3 |
Abstract:
The pyrolysis of liquid n-hexadecane was studied on various catalysts with selective microwave (MW) heating of a catalyst possessing much greater microwave absorption capacity than the long-chain hydrocarbon studied. This method permits rapid heating of the catalyst to temperatures much higher than 400 °C, leading to reflux of the liquid substrate, movement of the catalyst granules within the substrate, and chemical transformations (cracking) of hexadecane. High pyrolysis selectivity relative to α-olefins was found on various catalysts such as magnetic microspheres (coal combustion ash), Al2O3/Al, and Pd/KTP (glass fiber). This behavior may be attributed to tempering of the primary products in the bulk of the liquid reagent. Furthermore, MW pyrolysis on magnetic microspheres was found to be accompanied by formation of rather thick carbon microfibers with diameter 300–500 nm.
Cite:
Udalov E.I.
, Bolotov V.A.
, Tanashev Y.Y.
, Chernousov Y.D.
, Parmon V.N.
Pyrolysis of Liquid Hexadecane with Selective Microwave Heating of the Catalyst
Theoretical and Experimental Chemistry. 2011. V.46. N6. P.384-392. DOI: 10.1007/s11237-011-9169-y WOS Scopus РИНЦ ANCAN OpenAlex
Pyrolysis of Liquid Hexadecane with Selective Microwave Heating of the Catalyst
Theoretical and Experimental Chemistry. 2011. V.46. N6. P.384-392. DOI: 10.1007/s11237-011-9169-y WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Удалов Е.И.
, Болотов В.А.
, Танашев Ю.Ю.
, Черноусов Ю.Д.
, Пармон В.Н.
Пиролиз жидкого гексадекана в условиях селективного нагрева катализатора СВЧ-излучением
Теоретическая и экспериментальная химия. 2010. Т.46. №6. С.370-377. РИНЦ
Пиролиз жидкого гексадекана в условиях селективного нагрева катализатора СВЧ-излучением
Теоретическая и экспериментальная химия. 2010. Т.46. №6. С.370-377. РИНЦ
Dates:
| Submitted: | Oct 13, 2010 |
| Published print: | Jan 1, 2011 |
| Published online: | Mar 19, 2011 |
Identifiers:
| Web of science: | WOS:000288959700006 |
| Scopus: | 2-s2.0-79953200753 |
| Elibrary: | 16983886 |
| Chemical Abstracts: | 2011:400325 |
| Chemical Abstracts (print): | 154:463676 |
| OpenAlex: | W2143720631 |