Perovskite-Like Catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for Wet Peroxide Oxidation of Phenol | Sciact - CRIS-система Института катализа

Perovskite-Like Catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for Wet Peroxide Oxidation of Phenol Научная публикация

Журнал

Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883

Вых. Данные

Год: 2016, Том: 180, Страницы: 86-93 Страниц : 8 DOI: 10.1016/j.apcatb.2015.05.055

Ключевые слова

LaCuO3; LaFeO3; Perovskite-like oxides; Phenol; Wet peroxide oxidation

Авторы

Taran Oxana P. ^1,2 , Ayusheev Artemiy B. ¹ , Ogorodnikova Olga L. ¹ , Prosvirin Igor P. ^1,3 , Isupova Lyubov A. ¹ , Parmon Valentin N. ^1,3

Организации

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, prosp. Lavrentieva, 5, 630090 Novosibirsk, Russia
2	Novosibirsk State Technical University, prosp. K. Marx, 20, Novosibirsk 630092, Russia
3	Novosibirsk State University, Pirogova st., 2, Novosibirsk 630090, Russia

Информация о финансировании (1)

Российский научный фонд

14-13-01155

The catalytic behavior of perovskite-like oxides LaBO3 (B = Cu, Fe, Co, Ni, Mn) prepared by the Pecini method were examined in wet peroxide oxidation of phenol as a model organic substrate. The study showed the activity of only LaCuO3 and LaFeO3 perovskite-like catalysts, Cu-containing catalysts being more active, though Fe-containing being more stable. The leaching test proved the heterogeneous nature of the catalyst action. The long-term experiments revealed the acceptable stability of the LaFeO3 catalyst. XRD studies of the spent samples demonstrated the stability of the perovskite-like structure of the catalysts during the reaction. The assumption about the nature of the active sites and the possible mechanism of the reaction was proposed based on of the XPS study.

Taran O.P. , Ayusheev A.B. , Ogorodnikova O.L. , Prosvirin I.P. , Isupova L.A. , Parmon V.N.
Perovskite-Like Catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for Wet Peroxide Oxidation of Phenol
Applied Catalysis B: Environmental. 2016. V.180. P.86-93. DOI: 10.1016/j.apcatb.2015.05.055 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	7 мар. 2015 г.
Принята к публикации:	29 мая 2015 г.
Опубликована online:	12 июн. 2015 г.
Опубликована в печати:	1 янв. 2016 г.

Web of science:	WOS:000362379800011
Scopus:	2-s2.0-84934962957
РИНЦ:	24475775
Chemical Abstracts:	2015:1028788
Chemical Abstracts (print):	163:433062
OpenAlex:	W978985481

БД	Цитирований
Web of science	134
Scopus	146
РИНЦ	145
OpenAlex	152