EXAFS Study of Pd/Sibunit and Pd–Ga/Sibunit Catalysts for Liquid-Phase Hydrogenation of Acetylene to Ethylene Full article
| Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2015, Volume: 403, Pages: 10-14 Pages count : 5 DOI: 10.1016/j.molcata.2015.03.014 | ||||
| Tags | EXAFS spectroscopy, Pd-Ga phase, Pd/Sibunit catalysts, Selective liquid-phase hydrogenation of acetylene | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 14-03-90032 |
| 2 | The Ministry of Education and Science of the Russian Federation |
Abstract:
A series of catalysts Pd/Sibunit and Pd–Ga/Sibunit were prepared by impregnation with joint solutions of palladium and gallium nitrates in ethanol. The state of the active component and catalytic properties of the samples were studied in the liquid-phase hydrogenation of acetylene. The EXAFS method showed that the active component in the gallium-modified catalysts exists in the form of a non-stoichiometric Pd–Ga solid solution. The activity of the catalysts was found to be determined by the ratio Pd:Ga. It was shown that at the molar ratios Ga:Pd > 0.5:1, the catalytic activity is reduced by blocking the surface of the bimetallic particles by gallium oxide.
Cite:
Smirnova N.S.
, Shlyapin D.A.
, Shitova N.B.
, Kochubey D.I.
, Tsyrulʹnikov P.G.
EXAFS Study of Pd/Sibunit and Pd–Ga/Sibunit Catalysts for Liquid-Phase Hydrogenation of Acetylene to Ethylene
Journal of Molecular Catalysis A: Chemical. 2015. V.403. P.10-14. DOI: 10.1016/j.molcata.2015.03.014 WOS Scopus РИНЦ ANCAN OpenAlex
EXAFS Study of Pd/Sibunit and Pd–Ga/Sibunit Catalysts for Liquid-Phase Hydrogenation of Acetylene to Ethylene
Journal of Molecular Catalysis A: Chemical. 2015. V.403. P.10-14. DOI: 10.1016/j.molcata.2015.03.014 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Dec 8, 2014 |
| Accepted: | Mar 19, 2015 |
| Published online: | Mar 21, 2015 |
| Published print: | Jul 1, 2015 |
Identifiers:
| Web of science: | WOS:000354588600002 |
| Scopus: | 2-s2.0-84926068659 |
| Elibrary: | 27562333 |
| Chemical Abstracts: | 2015:522115 |
| Chemical Abstracts (print): | 162:514108 |
| OpenAlex: | W2063578324 |