Acetone and Ethanol Vapor Oxidation via Negative Atmospheric Corona Discharge over Titania-Based Catalysts Научная публикация
| Журнал |
Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883 |
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| Вых. Данные | Год: 2016, Том: 183, Страницы: 18-27 Страниц : 10 DOI: 10.1016/j.apcatb.2015.10.025 | ||||||
| Ключевые слова | Copper oxide, Manganese oxide, NTP, Post-plasma catalysis, Titanium dioxide, VOCs | ||||||
| Авторы |
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| Организации |
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Информация о финансировании (4)
| 1 | Федеральное агентство научных организаций России | V.44.2.11. |
| 2 | Министерство образования и науки Российской Федерации | 8440 |
| 3 | Совет по грантам Президента Российской Федерации | НШ-1183.2014.3 |
| 4 | Фонд «Сколково» | 3 от 25.12.2014 |
Реферат:
The paper is devoted to the oxidation of acetone and ethanol vapors by means of an optimized negative atmospheric corona discharge combined with TiO2-based catalysts located in a post-plasma position. A series of studied samples includes CuO-MnO2/TiO2, CuO/TiO2 and MnO2/TiO2 with 3 wt% of copper oxide and 6.8 wt% of manganese oxide. Experiments were performed at room temperature in a closed 404-L chamber with a ∼0.9-L active plasma region. It was shown that the use of the catalysts can provide a significant reduction in the concentrations of ozone and oxidation byproducts and a three-fold increased conversion of the reactants. It was unexpectedly found that copper oxide, as an active agent, did not significantly change the effect of post-plasma-located TiO2. The manganese-containing sample was found to be the best catalyst at the conditions considered. The presence of this catalyst in the post-plasma position inhibits the formation of unwanted products (O3 and CO) and promotes the deep oxidation of acetone and ethanol with increased selectivity toward CO2.
Библиографическая ссылка:
Lyulyukin M.N.
, Besov A.S.
, Vorontsov A.V.
Acetone and Ethanol Vapor Oxidation via Negative Atmospheric Corona Discharge over Titania-Based Catalysts
Applied Catalysis B: Environmental. 2016. V.183. P.18-27. DOI: 10.1016/j.apcatb.2015.10.025 WOS Scopus РИНЦ CAPlusCA OpenAlex
Acetone and Ethanol Vapor Oxidation via Negative Atmospheric Corona Discharge over Titania-Based Catalysts
Applied Catalysis B: Environmental. 2016. V.183. P.18-27. DOI: 10.1016/j.apcatb.2015.10.025 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 6 июл. 2015 г. |
| Принята к публикации: | 12 окт. 2015 г. |
| Опубликована online: | 23 окт. 2015 г. |
| Опубликована в печати: | 1 апр. 2016 г. |
Идентификаторы БД:
| Web of science: | WOS:000367106200003 |
| Scopus: | 2-s2.0-84984652057 |
| РИНЦ: | 26671399 |
| Chemical Abstracts: | 2015:1718794 |
| Chemical Abstracts (print): | 163:669926 |
| OpenAlex: | W1754662869 |