The Double-Route Model of Oscillatory Phenomena in the NO + H2 Reaction on Noble Metal Surfaces Научная публикация
| Журнал |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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| Вых. Данные | Год: 2013, Том: 143, Номер: 8, Страницы: 817-828 Страниц : 12 DOI: 10.1007/s10562-013-1037-z | ||
| Ключевые слова | Kinetic modelling, NOx reduction, Oscillations, Reaction intermediates, Surface reaction kinetics | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский фонд фундаментальных исследований | 11-03-00366 |
Реферат:
The conventional mechanism of oscillatory phenomena in the NO + H2 reaction on noble metals is supplemented with the temporal reaction route, providing fast removal of atomic nitrogen from saturated Nad layer via NHad species as a catalyst. The total sum of lost valences at a given adsorption site is taken as a degree of local surface imperfection. A semi-empirical evaluation of this approach regards an enormous advantage of Nad atoms at a grain boundary against perfect terraces in the activity of NHad formation as a driving force of both spatiotemporal and rate oscillations. Besides, NHad species are expected to obey an “easy-come-easy-go” principle enabling their ready formation as well as high diffusivity and reactivity. Mathematical modelling at fixed realistic step constants reveals three kinetic region-attractors related to a steady state, regular oscillations, and total reaction suppression by adsorbed oxygen atoms.
Библиографическая ссылка:
Cholach A.R.
, Bulgakov N.N.
The Double-Route Model of Oscillatory Phenomena in the NO + H2 Reaction on Noble Metal Surfaces
Catalysis Letters. 2013. V.143. N8. P.817-828. DOI: 10.1007/s10562-013-1037-z WOS Scopus РИНЦ CAPlusCA OpenAlex
The Double-Route Model of Oscillatory Phenomena in the NO + H2 Reaction on Noble Metal Surfaces
Catalysis Letters. 2013. V.143. N8. P.817-828. DOI: 10.1007/s10562-013-1037-z WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 19 сент. 2012 г. |
| Принята к публикации: | 29 мая 2013 г. |
| Опубликована online: | 13 июн. 2013 г. |
| Опубликована в печати: | 1 авг. 2013 г. |
Идентификаторы БД:
| Web of science: | WOS:000321873200010 |
| Scopus: | 2-s2.0-84880277343 |
| РИНЦ: | 20443658 |
| Chemical Abstracts: | 2013:937039 |
| Chemical Abstracts (print): | 159:155528 |
| OpenAlex: | W1995272382 |