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Titanium Salan/Salalen Complexes: The Twofaced Janus of Asymmetric Oxidation Catalysis Научная публикация

Журнал Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691
Вых. Данные Год: 2016, Том: 16, Номер: 2, Страницы: 924-939 Страниц : 16 DOI: 10.1002/tcr.201500273
Ключевые слова asymmetric oxidation, chirality, esomeprazole, hydrogen peroxide, titanium
Авторы Talsi Evgenii P. 1,2 , Bryliakova (Sametova) Anna A. 2 , Bryliakov Konstantin P. 1,2
Организации
1 Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090 (Russia)
2 Chemistry Department, Novosibirsk State University, Pirogova 2, Novosibirsk 630090 (Russia)

Информация о финансировании (2)

1 Федеральное агентство научных организаций России V.44.2.4.
2 Российский фонд фундаментальных исследований 14-03-00102

Реферат: Optically pure chiral epoxides and sulfoxides are ubiquitous building blocks in fine organic synthesis, employed in the pharmaceutical, agrochemical, and cosmetic industries. On the road to chiral epoxides and sulfoxides, efficient and stereoselective transition metal-based catalysts are the most promising guides. Among transition metals, we favor titanium for its cheapness and availability, nontoxicity, and well-known ability to catalyze a variety of stereoselective transformations, including oxidations with environmentally benign H2 O2 . In this personal account, we summarize the state-of-the-art of rational design of chiral titanium(IV) salan and salalen catalysts, and investigations of their catalytic reactivities and stereoselectivities in the epoxidations of olefins and oxidations of thioethers, unraveling the peculiarities and mechanisms of their catalytic action.
Библиографическая ссылка: Talsi E.P. , Bryliakova (Sametova) A.A. , Bryliakov K.P.
Titanium Salan/Salalen Complexes: The Twofaced Janus of Asymmetric Oxidation Catalysis
Chemical Record. 2016. V.16. N2. P.924-939. DOI: 10.1002/tcr.201500273 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Даты:
Поступила в редакцию: 6 нояб. 2015 г.
Опубликована online: 15 мар. 2016 г.
Опубликована в печати: 1 апр. 2016 г.
Идентификаторы БД:
Web of science: WOS:000374765700023
Scopus: 2-s2.0-84961282112
РИНЦ: 27136882
Chemical Abstracts: 2016:436650
PMID (PubMed): 26991421
OpenAlex: W2303126780
Цитирование в БД:
БД Цитирований
Web of science 16
Scopus 17
РИНЦ 17
OpenAlex 17
Альметрики: