Influence of Particle Size on the Magnetic Properties of Copper(II) Nitrate Complex with 2-(N-Acetylamino)-6-Methylpyridine | Sciact - CRIS-system of Boreskov Institute of Catalysis

Influence of Particle Size on the Magnetic Properties of Copper(II) Nitrate Complex with 2-(N-Acetylamino)-6-Methylpyridine Full article

Journal

Applied Magnetic Resonance
ISSN: 0937-9347 , E-ISSN: 1613-7507

Output data

Year: 2015, Volume: 46, Number: 2, Pages: 337-347 Pages count : 11 DOI: 10.1007/s00723-014-0637-0

Tags

Coordination compounds Copper nitrate complexes Crystalline samples Electron paramagnetic resonances (EPR) Frozen solutions Mesoporous structures Nano-sized particles Single crystal X-ray diffraction analysis

Authors

Antonova O.V. ¹ , Nadolinny V.A. ¹ , Berezin S.A. ^1,2 , Lider E.V. ^1,2 , Lavrenova L.G. ^1,2 , Melgunov M.S. ³

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090 Novosibirsk, Russia
2	Novosibirsk State University, 2, Pirogova Str, 630090 Novosibirsk, Russia
3	Boreskov Institute of Catalysis SB RAS, 5, Acad. Lavrentiev Ave, 630090 Novosibirsk, Russia

Funding (4)

1	Russian Foundation for Basic Research	12-03-31343
2	Russian Foundation for Basic Research	14-03-31539
3	Russian Foundation for Basic Research	14-03-90006
4	The Ministry of Education and Science of the Russian Federation	02.740.11.0628

The coordination compound of copper nitrate [CuL2(H2O)](NO3)2 with 2-(N-acetylamino)-6-methylpyridine (L) of the composition [CuL2(H2O)](NO3)2 has been prepared and investigated by single-crystal X-ray diffraction analysis and electron paramagnetic resonance (EPR) measurements. Crystalline samples, frozen solution in ethanol, thin films on quartz substrates and nanosized particles in mesoporous structures were investigated. The observed EPR spectra of [CuL2(H2O)](NO3)2 with a mesoporous structure and a pore diameter of 4 nm demonstrates that only dimers are realized in this matrix, but in a mesoporous structure with a pore diameter of 9 nm, seed crystals are formed together with dimers.

Antonova O.V. , Nadolinny V.A. , Berezin S.A. , Lider E.V. , Lavrenova L.G. , Melgunov M.S.
Influence of Particle Size on the Magnetic Properties of Copper(II) Nitrate Complex with 2-(N-Acetylamino)-6-Methylpyridine
Applied Magnetic Resonance. 2015. V.46. N2. P.337-347. DOI: 10.1007/s00723-014-0637-0 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 7, 2014
Published online:	Jan 8, 2015
Published print:	Mar 1, 2015

Web of science:	WOS:000350284300008
Scopus:	2-s2.0-84925462818
Elibrary:	24019665
Chemical Abstracts:	2015:115471
Chemical Abstracts (print):	163:251353
OpenAlex:	W2094014105

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Web of science	1
Scopus	1
Elibrary	1
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