Effect of Cis/Trans Isomerism on Selective Oxidation of Olefins with Nitrous Oxide Научная публикация
| Журнал |
Tetrahedron
ISSN: 0040-4020 , E-ISSN: 1464-5416 |
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| Вых. Данные | Год: 2016, Том: 72, Номер: 19, Страницы: 2501-2506 Страниц : 6 DOI: 10.1016/j.tet.2016.03.084 | ||||
| Ключевые слова | Cycloaddition, Isomers, Nitrous oxide, Olefins, Oxidation | ||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Российский фонд фундаментальных исследований | 14-03-31052 |
| 2 | Федеральное агентство научных организаций России | V.44.2.3. |
Реферат:
Liquid phase oxidation of olefins with nitrous oxide is a promising synthetic route to ketones. The effect
of cis/trans isomerism on the reactivity of olefins towards N2O and on the reaction mechanism was
studied for the first time using 3-heptene oxidation as an example. Our experimental study revealed that
cis- and trans-isomers of 3-heptene have similar reactivity and yield the same set of products. However,
the cis/trans isomerism of the olefin has a pronounced effect on the reaction route involving the cleavage
of the initial C]C bond and, accordingly, on the products ratio. The yield of ketones is lower for the transisomer
due to higher contribution of the cleavage route.
Библиографическая ссылка:
Ivanov D.
, Babushkin D.
, Semikolenov S.
, Malykhin S.
, Kharitonov A.
, Dubkov K.
Effect of Cis/Trans Isomerism on Selective Oxidation of Olefins with Nitrous Oxide
Tetrahedron. 2016. V.72. N19. P.2501-2506. DOI: 10.1016/j.tet.2016.03.084 WOS Scopus РИНЦ OpenAlex CAPlusCA
Effect of Cis/Trans Isomerism on Selective Oxidation of Olefins with Nitrous Oxide
Tetrahedron. 2016. V.72. N19. P.2501-2506. DOI: 10.1016/j.tet.2016.03.084 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 28 янв. 2016 г. |
| Принята к публикации: | 24 мар. 2016 г. |
| Опубликована online: | 26 мар. 2016 г. |
| Опубликована в печати: | 12 мая 2016 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000375164000017 |
| ≡ Scopus: | 2-s2.0-84962469702 |
| ≡ РИНЦ: | 26983832 |
| ≡ OpenAlex: | W2310850176 |
| ≡ Chemical Abstracts: | 2016:571786 |
| ≡ Chemical Abstracts (print): | 164:495594 |