Theoretical and Experimental Study of Methane Partial Oxidation to Syngas in Catalytic Membrane Reactor with Asymmetric Oxygen-Permeable Membrane | Sciact - CRIS-система Института катализа

Theoretical and Experimental Study of Methane Partial Oxidation to Syngas in Catalytic Membrane Reactor with Asymmetric Oxygen-Permeable Membrane Научная публикация

Конференция

12th International Conference on Catalysis in Membrane Reactors
22-25 июн. 2015 , Szczecin

Журнал

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Вых. Данные

Год: 2016, Том: 268, Страницы: 103-110 Страниц : 8 DOI: 10.1016/j.cattod.2016.01.005

Ключевые слова

Catalytic membrane reactor, Mathematical modeling, Mixed ionic-electronic conductivity, Nanocomposites, Oxygen-permeable membrane, Partial oxidation of methane, Syngas production

Авторы

Shelepova E. ^1,2 , Vedyagin A. ^1,2 , Sadykov V. ^1,3 , Mezentseva N. ^1,3 , Fedorova Y. ¹ , Smorygo O. ⁴ , Klenov O. ¹ , Mishakov I. ^1,2,3

Организации

1	Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Science, Pr. Ac. Lavrentieva, 5, Novosibirsk 630090, Russian Federation
2	National Research Tomsk Polytechnic University, Lenin Avenue, 30, Tomsk, 634050, Russian Federation
3	Novosibirsk State University, Pirogova str., 2, Novosibirsk 630090, Russian Federation
4	Institute of Powder Metallurgy, Platonov str., 41, Minsk 220005, Belarus

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	V.45.3.2.
2	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO

This paper presents results of theoretical and experimental research concerning synthesis of multilayer asymmetric oxygen-permeable membrane and its application for partial oxidation of methane. The membrane is based on macroporous Ni-Al foam substrate with three layers of perovskite-fluorite nanocomposites with graded (meso-micro) porosity, thin dense MnFe2O4–Ce0.9Gd0.1O2 layer and porous layer of LaNi0.9Pt0.1O3/Pr0.3Ce0.35Zr0.35O2-x catalyst. Testing of membrane in methane partial oxidation process demonstrates a good and stable performance. The mathematical modeling of the methane partial oxidation process in the catalytic membrane reactor has been provided. The developed model was applied to find the process (temperature, gas flow rates, etc.) and membrane (pore diameter of porous layer, thickness of porous layer) parameters corresponding to highest methane conversion and syngas selectivity.

Shelepova E. , Vedyagin A. , Sadykov V. , Mezentseva N. , Fedorova Y. , Smorygo O. , Klenov O. , Mishakov I.
Theoretical and Experimental Study of Methane Partial Oxidation to Syngas in Catalytic Membrane Reactor with Asymmetric Oxygen-Permeable Membrane
Catalysis Today. 2016. V.268. P.103-110. DOI: 10.1016/j.cattod.2016.01.005 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	28 авг. 2015 г.
Принята к публикации:	5 янв. 2016 г.
Опубликована online:	3 февр. 2016 г.
Опубликована в печати:	15 июн. 2016 г.

Web of science:	WOS:000375034900013
Scopus:	2-s2.0-85027921639
РИНЦ:	26782174
Chemical Abstracts:	2016:139875
Chemical Abstracts (print):	164:451542
OpenAlex:	W2261467684

БД	Цитирований
Web of science	30
Scopus	34
РИНЦ	32
OpenAlex	34