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New Composite Sorbents of Water and Methanol “Salt in Anodic Alumina”: Evaluation for Adsorption Heat Transformation Full article

Journal Energy
ISSN: 0360-5442 , E-ISSN: 1873-6785
Output data Year: 2016, Volume: 106, Pages: 231-239 Pages count : 9 DOI: 10.1016/j.energy.2016.03.050
Tags Adsorption heat transformation, Anodic alumina, Composite sorbents, Energy saving technology, Methanol, Water
Authors Grekova A.D. 1,2 , Girnik I.S. 1,2 , Nikulin V.V. 1,2 , Tokarev M.M. 1 , Gordeeva L.G. 1,2 , Aristov Yu.I. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Ac. Lavrentieva av. 5, Novosibirsk, 630090, Russia
2 Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russia

Funding (1)

1 Russian Foundation for Basic Research 14-08-31710

Abstract: Development of new adsorbents of water and methanol specialised for AHT (adsorption heat transformation) can essentially advance this emerging low-carbon technology. This paper addresses the synthesis of novel composite sorbents based on an AA (anodic alumina) layer impregnated with hygroscopic salts, and the study of their ability to sorb water and methanol vapours. This work consists of the three parts: (1) synthesis and comparison of AA/Al sandwiches obtained with various electrolytes (sulphuric, oxalic, and phosphoric acids); (2) preparation of salt/AA composites (salt = CaCl2 and LiCl) and study of their sorption equilibrium and dynamics with water and methanol vapours; and (3) evaluation of the new sorbents feasibility for AHT applications. The results obtained show that a) the new AA-based composites could be interesting for making compact AHT units with short working cycles, and b) still more R&D are necessary for further progress towards practical implementation of the new sorbents.
Cite: Grekova A.D. , Girnik I.S. , Nikulin V.V. , Tokarev M.M. , Gordeeva L.G. , Aristov Y.I.
New Composite Sorbents of Water and Methanol “Salt in Anodic Alumina”: Evaluation for Adsorption Heat Transformation
Energy. 2016. V.106. P.231-239. DOI: 10.1016/j.energy.2016.03.050 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Aug 23, 2015
Accepted: Mar 11, 2016
Published online: Apr 4, 2016
Published print: Jul 1, 2016
Identifiers:
Web of science: WOS:000378659700023
Scopus: 2-s2.0-84962128718
Elibrary: 27145467
Chemical Abstracts: 2016:527481
Chemical Abstracts (print): 166:539492
OpenAlex: W2323879904
Citing:
DB Citing
Web of science 15
Scopus 16
Elibrary 16
OpenAlex 16
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