Catalytic Reaction of Diethyl Disulfide with Methanol | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Reaction of Diethyl Disulfide with Methanol Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2016, Volume: 52, Number: 3, Pages: 307-311 Pages count : 5 DOI: 10.1134/S1070428016030027

Tags

Hydrogen Sulfide; Dimethyl Sulfide; Dimethyl Disulfide; Methanethiol; Ethanethiol

Authors

Mashkina A.V. ¹ , Khairulina L.N. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akad. Lavrent’eva 5, Novosibirsk, 630090 Russia

Diethyl disulfide reacted with methanol in the presence of solid acid catalysts at 250–350°C to give dimethyl, ethyl methyl, and diethyl sulfides. The most active catalysts were those containing simultaneously moderate basic sites, strong Lewis acid sites, and some amount of strong protonic acid sites. These catalysts ensured a total selectivity of 99% for dialkyl sulfides.

Mashkina A.V. , Khairulina L.N.
Catalytic Reaction of Diethyl Disulfide with Methanol
Russian Journal of Organic Chemistry. 2016. V.52. N3. P.307-311. DOI: 10.1134/S1070428016030027 WOS Scopus РИНЦ ANCAN OpenAlex

Машкина А.В. , Хайрулина Л.Н.
Каталитическая реакция диэтилдисульфида с метанолом
Журнал органической химии. 2016. Т.52. №3. С.327-331. РИНЦ

Submitted:	Nov 9, 2015
Published print:	Mar 1, 2016
Published online:	May 17, 2016

Web of science:	WOS:000376247900002
Scopus:	2-s2.0-84970028265
Elibrary:	27155460
Chemical Abstracts:	2016:790091
Chemical Abstracts (print):	165:31203
OpenAlex:	W2383285254

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