Behavior of Some Deep Oxidation Catalysts under Extreme Conditions. 1. Comparison of Resistance to Thermal Shock and SO2 Poisoning Научная публикация
| Журнал |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Вых. Данные | Год: 1998, Том: 167, Номер: 1, Страницы: 31-37 Страниц : 7 DOI: 10.1016/S0926-860X(97)00293-7 | ||||
| Ключевые слова | Alumina-manganese oxide catalyst, Deep oxidation, SO2 poisoning resistance, Thermostability | ||||
| Авторы |
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| Организации |
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Реферат:
The activity of catalysts before and after heat treatment up to 950°C was measured in model reactions of methane and butane deep oxidation. The poison stability was investigated by examining the catalysts in deep oxidation of methane (1 vol% in air) in the presence of SO2 (0.05 vol%). The alumina-manganese oxide catalyst was found to be the most resistant to overheating. It lowered the activity in deep methane oxidation ∼2.5 times only after calcination at 950°C for 800 h. The more poison stable samples were found to be alumina-palladium and perovskite (on the base of LaMnO3) catalysts. The activity of more thermostable alumina-manganese oxide catalyst is lowered up to zero activity in deep oxidation of methane at 500°C. But at reaction temperature 700°C the catalyst is sufficiently stable to poisoning.
Библиографическая ссылка:
Tsyrulnikov P.G.
, Kovalenko O.N.
, Gogin L.L.
, Starostina T.G.
, Noskov A.S.
, Kalinkin A.V.
, Krukova G.N.
, Tsybulya S.V.
, Kudrya E.N.
, Bubnov A.V.
Behavior of Some Deep Oxidation Catalysts under Extreme Conditions. 1. Comparison of Resistance to Thermal Shock and SO2 Poisoning
Applied Catalysis A: General. 1998. V.167. N1. P.31-37. DOI: 10.1016/S0926-860X(97)00293-7 WOS Scopus РИНЦ CAPlusCA OpenAlex
Behavior of Some Deep Oxidation Catalysts under Extreme Conditions. 1. Comparison of Resistance to Thermal Shock and SO2 Poisoning
Applied Catalysis A: General. 1998. V.167. N1. P.31-37. DOI: 10.1016/S0926-860X(97)00293-7 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 25 февр. 1997 г. |
| Принята к публикации: | 18 сент. 1997 г. |
| Опубликована в печати: | 5 февр. 1998 г. |
| Опубликована online: | 15 авг. 2000 г. |
Идентификаторы БД:
| Web of science: | WOS:000071867700005 |
| Scopus: | 2-s2.0-0002736464 |
| РИНЦ: | 13698729 |
| Chemical Abstracts: | 1998:43943 |
| Chemical Abstracts (print): | 128:117130 |
| OpenAlex: | W2040095254 |