Catalytic Filamentous Carbon: Structural and Textural Properties | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Filamentous Carbon: Structural and Textural Properties Full article

Journal

Carbon
ISSN: 0008-6223 , E-ISSN: 1873-3891

Output data

Year: 2003, Volume: 41, Number: 8, Pages: 1605-1615 Pages count : 11 DOI: 10.1016/S0008-6223(03)00115-5

Tags

A. Carbon filaments, B. Chemical vapor deposition, C. Raman spectroscopy, Transmission electron microscopy, D. Texture

Authors

Reshetenko T.V. ¹ , Avdeeva L.B. ¹ , Ismagilov Z.R. ¹ , Pushkarev V.V. ² , Cherepanova S.V. ¹ , Chuvilin A.L. ¹ , Likholobov V.A. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akad. Lavrentieva 5, Novosibirsk 630090, Russia
2	Department of Chemical and Petroleum Engineering, University of Pittsburgh, 1249 Benedum Hall, Pittsburgh, PA 15260, USA

Funding (2)

1	Civilian Research and Development Foundation	REC-008
2	Netherlands Organisation for Scientific Research

Catalytic filamentous carbon (CFC) synthesized by the decomposition of methane over iron subgroup metal catalysts (Ni, Co, Fe or their alloys) is a new family of mesoporous carbon materials possessing the unique structural and textural properties. Microstructural properties of CFC (arrangement of the graphite planes in filaments) are shown to depend on the nature of catalyst for methane decomposition. These properties widely vary for different catalysts: the angle between graphite planes and the filament axis can be 0° (Fe–Co–Al2O3), 15° (Co–Al2O3), 45° (Ni–Al2O3), 90° (Ni–Cu–Al2O3). The textural properties of CFC depend both on the catalyst nature and the conditions of methane decomposition (T, °C). The micropore volume in CFC is very low, 0.001–0.022 cm3 g−1 at the total pore volume of 0.26–0.59 cm3 g−1. Nevertheless, the BET surface area may reach 318 m2 g−1. Results of the TEM (HRTEM), XRD, Raman spectroscopic, SEM and adsorption studies of the structural and textural properties of CFC are discussed.

Reshetenko T.V. , Avdeeva L.B. , Ismagilov Z.R. , Pushkarev V.V. , Cherepanova S.V. , Chuvilin A.L. , Likholobov V.A.
Catalytic Filamentous Carbon: Structural and Textural Properties
Carbon. 2003. V.41. N8. P.1605-1615. DOI: 10.1016/S0008-6223(03)00115-5 WOS Scopus РИНЦ ANCAN OpenAlex

Published print:	Jan 1, 2003
Submitted:	Jan 25, 2003
Accepted:	Mar 3, 2003
Published online:	May 30, 2003

Web of science:	WOS:000183674700016
Scopus:	2-s2.0-0037603132
Elibrary:	13426927
Chemical Abstracts:	2003:425070
Chemical Abstracts (print):	139:186426
OpenAlex:	W1985247491

DB	Citing
Web of science	143
Scopus	152
Elibrary	162
OpenAlex	143