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Filamentous Carbon Templated SiO2-NiO Aerogel: Structure and Catalytic Properties for Direct Oxidation of Hydrogen Sulfide into Sulfur Научная публикация

Журнал Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Вых. Данные Год: 2000, Том: 70, Номер: 1-2, Страницы: 83-91 Страниц : 9 DOI: 10.1023/A:1019019317391
Ключевые слова Filamentous carbon, Hydrogen sulfide direct oxidation, Silica aerogol, Sol-gel method
Авторы Ermakova Marina A. 1 , Ermakov Dmitriy Yu. 1 , Lebedev Max Yu. 1 , Rudina Nina A. 1 , Kuvshinov Gennadiy G. 1
Организации
1 Boreskov Institute of Catalysis, Prosp. Ak. Lavrentieva 5, Novosibirsk 630090, Russia

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 99-03-32274

Реферат: Silica aerogels comprising nickel oxide nanoparticles were synthesized with no use of supercritical drying. A high specific surface area (more than 1000 m2/g), mesoporous structure and considerable stability to sintering up to 900 °C are characteristic of these aerogels. The aerogels were synthesized using the sol–gel method. Filamentous carbon was templated by silica, tetraethoxysilane being used for supplying silica. Carbon was burnt later. Analysis of the aerogel structure revealed the presence of silica nanotubes and nanofibers. Aerogel testing for direct oxidation of H2S into S0 demonstrated as high as 60% conversion of hydrogen sulfide at almost 100% selectivity under stoichiometric conditions at the temperature range of 300–350 °C and 73% conversion at 100% selectivity at a considerable excess of oxygen at 160 °C.
Библиографическая ссылка: Ermakova M.A. , Ermakov D.Y. , Lebedev M.Y. , Rudina N.A. , Kuvshinov G.G.
Filamentous Carbon Templated SiO2-NiO Aerogel: Structure and Catalytic Properties for Direct Oxidation of Hydrogen Sulfide into Sulfur
Catalysis Letters. 2000. V.70. N1-2. P.83-91. DOI: 10.1023/A:1019019317391 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 4 апр. 2000 г.
Принята к публикации: 11 сент. 2000 г.
Опубликована в печати: 1 дек. 2000 г.
Идентификаторы БД:
Web of science: WOS:000165179200014
Scopus: 2-s2.0-0034323315
РИНЦ: 13345491
Chemical Abstracts: 2001:3301
Chemical Abstracts (print): 134:105009
OpenAlex: W313977592
Цитирование в БД:
БД Цитирований
Web of science 9
Scopus 10
РИНЦ 10
OpenAlex 11
Альметрики: