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Hydroxylation of Benzene with Oxygen and Hydrogen over Catalysts Containing Group VIII Metals and Heteropoly Compounds Научная публикация

Журнал Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Вых. Данные Год: 2005, Том: 99, Номер: 1-2, Страницы: 193-198 Страниц : 6 DOI: 10.1016/j.cattod.2004.09.040
Ключевые слова Benzene, Hydrogen, Oxidation, Oxygen, Palladium, Platinum
Авторы Kuznetsova N.I. 1 , Kuznetsova L.I. 1 , Likholobov V.A. 2 , Pez G.P. 3
Организации
1 Boreskov Institute of Catalysis, Prosp. Lavrentieva, 5, Novosibirsk 630090, Russia
2 Institute of Hydrocarbon Processing, Neftezavodskaya St., 54, Omsk 644040, Russia
3 Air Products and Chemicals, Inc., Corporate Science and Technology Center, 7201 Hamilton Blvd., Allentown, PA 18195-1501, USA

Информация о финансировании (2)

1 Российский фонд фундаментальных исследований 03-03-32787
2 Совет по грантам Президента Российской Федерации НШ-2287.2003.3

Реферат: The vapor phase hydroxylation of benzene to phenol with a mixture of oxygen and hydrogen over silica supported bi-component catalysts containing Group VIII metals (M) and heteropoly compounds (HPC) was investigated. The productivity of the catalysts was ascertained for various metal and HPC combinations and a range of reaction conditions. The Pt–PMo12/SiO2 and Pd–PMo12/SiO2 catalysts of optimal composition provide up to 380 mol phenol/g-atom Pt or Pd/h. The observed catalysis appears to be associated with an interface between metal particles and those of the heteropoly compound, as illustrated by an HREM image of a Pt–PMo12/SiO2 sample.
Библиографическая ссылка: Kuznetsova N.I. , Kuznetsova L.I. , Likholobov V.A. , Pez G.P.
Hydroxylation of Benzene with Oxygen and Hydrogen over Catalysts Containing Group VIII Metals and Heteropoly Compounds
Catalysis Today. 2005. V.99. N1-2. P.193-198. DOI: 10.1016/j.cattod.2004.09.040 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована online: 15 дек. 2004 г.
Опубликована в печати: 15 янв. 2005 г.
Идентификаторы БД:
Web of science: WOS:000228114200024
Scopus: 2-s2.0-14644415980
РИНЦ: 13488577
Chemical Abstracts: 2005:224831
Chemical Abstracts (print): 142:448563
OpenAlex: W2073651226
Цитирование в БД:
БД Цитирований
Web of science 46
Scopus 50
РИНЦ 50
OpenAlex 48
Альметрики: