Solid-State 51V NMR for Characterization of Vanadium-Containing Systems | Sciact - CRIS-система Института катализа

Solid-State 51V NMR for Characterization of Vanadium-Containing Systems Обзор

Конференция

4th International Symposium on Group Five Compounds
10-12 апр. 2002 , Toledo

Журнал

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Вых. Данные

Год: 2003, Том: 78, Номер: 1-4, Страницы: 91-104 Страниц : 14 DOI: 10.1016/S0920-5861(02)00299-7, 10.1002/chin.200335200

Ключевые слова

51V NMR, Catalysts, Glasses, Individual compounds, MQMAS, SATRAS, Solid solutions, Solid-state nuclear magnetic resonance, STMAS, Ultra-high-speed MAS, Vanadium

Авторы

Lapina O.B. ¹ , Shubin A.A. ¹ , Khabibulin D.F. ¹ , Terskikh V.V. ¹ , Bodart P.R. ² , Amoureux J.-P. ²

Организации

1	Boreskov Institute of Catalysis, Prosp. Lavrentieva 5, 630090 Novosibirsk, Russia
2	Laboratoire de Dynamique et Structure des Matériaux Moléculaire, Universite des Sciences et Technologies de Lille, F-59655 Villeneuve d’Ascq, France

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	01-03-32364
2	International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union	PAI 04522WK

This overview paper includes both published and original data of the current state of the field of Full-size image (<1 K) NMR in solid-state chemistry. Advantages and shortcomings of different NMR techniques in their applications to vanadium are discussed on the examples of their application to various vanadia based systems (including individual highly crystalline compounds, solid solutions, glasses, catalysts). New correlations between local structure of vanadium atoms and NMR parameters allowing to discriminate at least seven different types of vanadium sites (tetrahedral sites of Q0, Q1 and Q2 types; trigonal pyramids of 3=1 and 3=2 (V2O5 like) types; tetragonal pyramids of 4=1, 4=2 types) are proposed. It is demonstrated that competent combination of different NMR approaches permits now not only to describe different vanadium sites in highly crystalline and amorphous materials, but also to insight into the structural aspects of disorder in crystallinity as well as to reveal the behavior of different functional groups at elevated temperatures. The influence of low valence vanadium atoms on Full-size image (<1 K) NMR spectra is also discussed.

Lapina O.B. , Shubin A.A. , Khabibulin D.F. , Terskikh V.V. , Bodart P.R. , Amoureux J.-P.
Solid-State 51V NMR for Characterization of Vanadium-Containing Systems
Catalysis Today. 2003. V.78. N1-4. P.91-104. DOI: 10.1016/S0920-5861(02)00299-7, 10.1002/chin.200335200 WOS Scopus РИНЦ CAPlusCA OpenAlex

Опубликована online:	14 февр. 2003 г.
Опубликована в печати:	28 февр. 2003 г.

Web of science:	WOS:000181816300009
Scopus:	2-s2.0-0037469733
РИНЦ:	13435032
Chemical Abstracts:	2003:215938
Chemical Abstracts (print):	139:16152
OpenAlex:	W2016960452

БД	Цитирований
Web of science	38
Scopus	41
РИНЦ	42
OpenAlex	40