Water Denitrification over Catalytic Membranes: Hydrogen Spillover and Catalytic Activity of Macroporous Membranes Loaded with Pd and Cu Научная публикация
| Конференция |
5th International Conference on Catalysis in Membrane Reactors 26-28 июн. 2002 , Dalian |
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| Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Вых. Данные | Год: 2003, Том: 82, Номер: 1-4, Страницы: 49-56 Страниц : 8 DOI: 10.1016/S0920-5861(03)00201-3 | ||||||
| Ключевые слова | Catalytic membrane, Hydrogen spillover, Palladium-copper catalytic system, Reaction mechanism, Reduction of aqueous nitrate ions | ||||||
| Авторы |
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| Организации |
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Реферат:
Mono- and bimetallic catalytic membranes were prepared via deposition of Pd and Cu onto macroporous polymeric membrane. The membranes were employed to catalyze the reaction of nitrate ions reduction by hydrogen in water. Monometallic Pd- and Cu-loaded membranes were poorly active in the reaction, while bimetallic (Pd+Cu)-loaded membranes exhibited high catalytic activity. Combination of monometallic Pd- and Cu-loaded membranes in one stack resulted in high catalytic activity, similar to that of bimetallic (Pd+Cu)-loaded membranes. The results of this study provide experimental support for a hypothesis on hydrogen spillover as a part of the molecular mechanism of nitrate ions reduction by hydrogen in water over palladium–copper catalytic system.
Библиографическая ссылка:
Ilinich O.M.
, Gribov E.N.
, Simonov P.A.
Water Denitrification over Catalytic Membranes: Hydrogen Spillover and Catalytic Activity of Macroporous Membranes Loaded with Pd and Cu
Catalysis Today. 2003. V.82. N1-4. P.49-56. DOI: 10.1016/S0920-5861(03)00201-3 WOS Scopus РИНЦ OpenAlex CAPlusCA
Water Denitrification over Catalytic Membranes: Hydrogen Spillover and Catalytic Activity of Macroporous Membranes Loaded with Pd and Cu
Catalysis Today. 2003. V.82. N1-4. P.49-56. DOI: 10.1016/S0920-5861(03)00201-3 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Опубликована online: | 25 июн. 2003 г. |
| Опубликована в печати: | 30 июл. 2003 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000185021000006 |
| ≡ Scopus: | 2-s2.0-0041630972 |
| ≡ РИНЦ: | 13421089 |
| ≡ OpenAlex: | W1975507771 |
| ≡ Chemical Abstracts: | 2003:595497 |
| ≡ Chemical Abstracts (print): | 139:311746 |