Cu+(H2) and Na+(H2) Adducts in Exchanged ZSM-5 Zeolites | Sciact - CRIS-система Института катализа

Cu+(H2) and Na+(H2) Adducts in Exchanged ZSM-5 Zeolites Научная публикация

Журнал

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Вых. Данные

Год: 2004, Том: 10, Номер: 23, Страницы: 2768-2769 Страниц : 2 DOI: 10.1039/b411053f

Ключевые слова

CARBON-MONOXIDE; IR; Cu-I-ZSM-5; ADSORPTION; COMPLEXES; ENERGIES; CLUSTERS; HYDROGEN; FTIR; H-2

Авторы

Spoto Giuseppe ^1,2 , Gribov Evgueni ¹ , Bordiga Silvia ^1,2 , Lamberti Carlo ^1,2 , Ricchiardi Gabriele ^1,2 , Scarano Domenica ^1,2 , Zecchina Adriano ^1,2

Организации

1	Dipartimento di Chimica IFM, Via P. Giuria 7, I-10125 Torino, Italy
2	NIS – Nanostructured Interfaces and Surfaces – Centre of Excellence, c/o Dipartimento di Chimica IFM

Cu(I) ions in Cu-ZSM-5 form Cu+(H2) complexes, stable at room temperature and sub-atmospheric H2 pressure, which do not have any homogeneous analogue except for matrix-isolated [Cu(η2-H2)Cl]. Comparison with the unstable Na+(H2) adducts formed in the parent Na-ZSM-5 zeolite allow the conclusion that the Cu(I)/H2 bond is governed by σ–π overlap forces.

Spoto G. , Gribov E. , Bordiga S. , Lamberti C. , Ricchiardi G. , Scarano D. , Zecchina A.
Cu+(H2) and Na+(H2) Adducts in Exchanged ZSM-5 Zeolites
Chemical Communications. 2004. V.10. N23. P.2768-2769. DOI: 10.1039/b411053f WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	20 июл. 2004 г.
Принята к публикации:	7 сент. 2004 г.
Опубликована online:	6 окт. 2004 г.
Опубликована в печати:	4 дек. 2004 г.

Web of science:	WOS:000225377100060
Scopus:	2-s2.0-11144269087
РИНЦ:	14564371
Chemical Abstracts:	2004:1037552
Chemical Abstracts (print):	142:184153
OpenAlex:	W2149834391

БД	Цитирований
Web of science	59
Scopus	60
OpenAlex	57