Synthesis of New Chiral Phosphorous- and Nitrogen-Containing Ligands From Resin Acids Full article
| Journal |
Chirality
ISSN: 0899-0042 , E-ISSN: 1520-636X |
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| Output data | Year: 2004, Volume: 16, Number: SUPPL., Pages: S40-S50 Pages count : 1 DOI: 10.1002/chir.20045 | ||||
| Tags | Asymmetric catalysis, Bisphosphines, Dehydroabietic acid, Diterpenes, Levopimaric acid, Thioureas, Ureas | ||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 04-03-32425 |
| 2 | Russian Foundation for Basic Research | 04-03-32063 |
| 3 | Council for Grants of the President of the Russian Federation | НШ-2020.2003.3 |
Abstract:
Starting from the phytogenic diterpenes, chiral phosphine, urea, and thiourea derivatives were synthesized. Using these new chiral ligands, Rh(I) and Ru(II) complexes were prepared and used as catalysts for the catalytic asymmetric hydrogenation of unsaturated carboxylic acids and asymmetric hydrogen-transfer reduction of carbonyl compounds. Although the enantiopurity of the products obtained was not high, it was demonstrated that chiral ligands derived from diterpenes could be used for asymmetric reduction.
Cite:
Khlebnikova T.B.
, Karpyshev N.N.
, Tolstikova O.V.
, Tolstikov A.G.
Synthesis of New Chiral Phosphorous- and Nitrogen-Containing Ligands From Resin Acids
Chirality. 2004. V.16. NSUPPL.. P.S40-S50. DOI: 10.1002/chir.20045 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Synthesis of New Chiral Phosphorous- and Nitrogen-Containing Ligands From Resin Acids
Chirality. 2004. V.16. NSUPPL.. P.S40-S50. DOI: 10.1002/chir.20045 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Dates:
| Submitted: | Oct 21, 2003 |
| Accepted: | Feb 23, 2004 |
| Published online: | Jun 25, 2004 |
Identifiers:
| Web of science: | WOS:000222912900007 |
| Scopus: | 2-s2.0-3242671481 |
| Elibrary: | 13452337 |
| Chemical Abstracts: | 2004:611323 |
| Chemical Abstracts (print): | 141:395681 |
| PMID: | 15239072 |
| OpenAlex: | W2074454493 |