Selective Low-Temperature Transformation of Methane into C2-C4 Alkenes in the Presence of a Hydrogen-Accumulating System | Sciact - CRIS-система Института катализа

Selective Low-Temperature Transformation of Methane into C2-C4 Alkenes in the Presence of a Hydrogen-Accumulating System Научная публикация

Журнал

Doklady Physical Chemistry
ISSN: 0012-5016 , E-ISSN: 1608-3121

Вых. Данные

Год: 1998, Том: 361, Номер: 4-6, Страницы: 276-279 Страниц : 4

Авторы

Tsodikov M.V. ¹ , Slivinskii E.V. ¹ , Mordovin V.P. ¹ , Shestakov A.F. ¹ , Kochubey D.I. ¹ , Ivanov V.P. ¹ , Bukhtenko O.V. ¹ , Navío J. ¹

Организации

1	Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29

Low-temperature conversion of CH4 in alkenes in the presence of H-accumulating system able to activate C-H bonds with subsequent removal of H from the reaction mixture was studied. The catalyst was a mixture of cylinders of highly purified Ti containing 0.4% wt. Ni and chips of highly purified Ti. The catalyst was activated by thermal treatment. Mechanism of formation of olefins is discussed. Conversion of methane at low temperature was 20% wt.; olefin content was 68-73% from it. 50-55% Wt. of all olefins was ethylene.

Tsodikov M.V. , Slivinskii E.V. , Mordovin V.P. , Shestakov A.F. , Kochubey D.I. , Ivanov V.P. , Bukhtenko O.V. , Navío J.
Selective Low-Temperature Transformation of Methane into C2-C4 Alkenes in the Presence of a Hydrogen-Accumulating System
Doklady Physical Chemistry. 1998. V.361. N4-6. P.276-279. Scopus РИНЦ

Цодиков М.В. , Сливинский Е.В. , Мордовин В.П. , Шестаков А.Ф. , Кочубей Д.И. , Иванов В.П. , Бухтенко О.В. , Навио Х.А.
Селективное низкотемпературное превращение метана в алкены C2-C4 в присутствии водородаккумулирующей системы
Доклады Академии наук. 1998. Т.361. №6. С.791-794. РИНЦ CAPlusCA

Поступила в редакцию:	11 февр. 1998 г.
Опубликована в печати:	1 авг. 1998 г.

Scopus:	2-s2.0-27144496180
РИНЦ:	13281071

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