High-Pressure Studies of CO Adsorption on Pd(111) by X-ray Photoelectron Spectroscopy and Sum-Frequency Generation Full article
| Journal |
The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207 |
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| Output data | Year: 2003, Volume: 107, Number: 15, Pages: 3522-3527 Pages count : 6 DOI: 10.1021/jp021992t | ||||
| Tags | Carbon monoxide; High pressure effects; Palladium; X ray photoelectron spectroscopy | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | German Research Foundation | SPP1091 |
Abstract:
High-pressure CO adsorption on Pd(111) was examined by X-ray photoelectron spectroscopy (XPS) and vibrational sum frequency generation (SFG) from 200 to 400 K, and in a pressure range from 10-6 to 1 mbar. Even in the millibar regime both methods indicated that CO adsorbed in “regular” adsorption sites such as hollow, bridge, and on-top. By combination of XPS and SFG, a quantitative analysis of CO coverages at various pressures was performed. At high pressure, no CO structures different from those known from UHV studies were observed. Also, no indications of CO dissociation or carbonyl formation were found under the given experimental conditions, provided that the CO gas was sufficiently cleaned.
Cite:
Kaichev V.V.
, Prosvirin I.P.
, Bukhtiyarov V.I.
, Unterhalt H.
, Rupprechter G.
, Freund H-J.
High-Pressure Studies of CO Adsorption on Pd(111) by X-ray Photoelectron Spectroscopy and Sum-Frequency Generation
The Journal of Physical Chemistry B. 2003. V.107. N15. P.3522-3527. DOI: 10.1021/jp021992t WOS Scopus РИНЦ ANCAN OpenAlex
High-Pressure Studies of CO Adsorption on Pd(111) by X-ray Photoelectron Spectroscopy and Sum-Frequency Generation
The Journal of Physical Chemistry B. 2003. V.107. N15. P.3522-3527. DOI: 10.1021/jp021992t WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Sep 6, 2002 |
| Published print: | Apr 1, 2003 |
Identifiers:
| Web of science: | WOS:000182167500026 |
| Scopus: | 2-s2.0-0037451812 |
| Elibrary: | 41796863 |
| Chemical Abstracts: | 2003:226968 |
| Chemical Abstracts (print): | 138:374494 |
| OpenAlex: | W1980897511 |