Mechanism for Selective Oxidation of Ethanol over V-Ti Catalyst - Conference attendances | Sciact - CRIS-system of Boreskov Institute of Catalysis

Mechanism for Selective Oxidation of Ethanol over V-Ti Catalyst Conference attendances

Language

Английский

Participant type

Устный

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Authors

Kaichev Vasily Vasilievich ¹ , Chesalov Yuriy Aleksandrovich ¹ , Saraev Andrey Aleksandrovich ¹ , Klyushin Alexander ² , Knop-Gericke Axel ² , Andrushkevich Tamara Vitalievna ¹ , Bukhtiyarov Valerii Ivanovich ¹

Affiliations

1	Boreskov Institute of Catalysis SB RAS
2	Fritz Haber Institute of the Max Planck Society

The selective oxidation of ethanol to acetaldehyde and acetic acid over a monolayer V2O5/TiO2 catalyst has been studied in situ using Fourier transform infrared spectroscopy and near ambient-pressure X-ray photoelectron spectroscopy. The data were complemented by temperature–programmed reaction spectroscopy and kinetic measurements in a flow reactor. Based on the obtained data the mechanism for the oxidation of ethanol over vanadia-titania catalysts is developed.

Kaichev V.V. , Chesalov Y.A. , Saraev A.A. , Klyushin A. , Knop-Gericke A. , Andrushkevich T.V. , Bukhtiyarov V.I.
Mechanism for Selective Oxidation of Ethanol over V-Ti Catalyst
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015