Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
Патенты
| Язык: |
Английский |
| Тип: |
Заявка на патент |
| Номер (11) |
WO 2014109777 A1 |
| Номер заявки (21): |
PCT/US2013/023861 |
| Дата подачи заявки (22): |
30 янв. 2013 г. |
| Дата начала отсчета срока действия патента (24): |
|
| Дата публикации патента (44,45,46): |
|
| Дата публикации заявки (43): |
17 июл. 2014 г. |
Desulfurization of hydrocarbon feeds is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A first fraction contains refractory organosulfur compounds, which boils at or above the target cut point temperature. A second fraction boiling below the target cut point temperature is substantially free of refractory sulfur-containing compounds. The second fraction is contacted with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. The first fraction is contacted with gaseous oxidizing agent over an oxidation catalyst having a formula CuxZn1-xAL2O4 in a gas phase catalytic oxidation reaction zone to convert the refractory organosulfur compounds to SOx and low sulfur hydrocarbons. The by-product SOx is subsequently removed, producing a stream containing a reduced level of organosulfur compounds.