Biomimetic Oxidation on Fe Complexes in Zeolites
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Конференция |
11th International Congress on Catalysis - 40th Anniversary
30 июн. - 5 июл. 1996
,
Baltimore
|
| Сборник |
11th International Congress on Catalysis - 40th Anniversary : Proceedings of the 11th ICC, 30 June-5 July 1996, Baltimore, MD, USA
Сборник,
1996.
1441 c. ISBN 9780444819475.
|
| Журнал |
Studies in Surface Science and Catalysis
ISSN: 0167-2991
|
| Вых. Данные |
Год: 1996,
Том: 101 A,
Страницы: 493-502
Страниц
: 10
DOI:
10.1016/S0167-2991(96)80260-6
|
| Ключевые слова |
N2O DECOMPOSITION; ZSM-5 ZEOLITE; OXO PROTEINS; IRON; HYDROXYLATION; BENZENE; MODELS; CYTOCHROME-P-450; MOSSBAUER; CENTERS |
| Авторы |
Panov Gennady I.
1
,
Sobolev Vladimir I.
1
,
Dubkov Konstantin A.
1
,
Kharitonov Alexander S.
1
|
| Организации |
| 1 |
Boreskov Institute of Catalysis
|
|
One-step hydroxylation of aromatic nucleus with nitrous oxide (N20) is among recently discovered organic reactions. A high efficiency of FeZSM-5 zeolites in this reaction relates to a pronounced biomimetic-type activity of iron complexes stabilized in ZSM-5 matrix. N20 decomposition on these complexes produces particular atomic oxygen form (a-oxygen), whose chemistry is similar to that performed by the active oxygen of enzyme monooxygenases. Room temperature oxidation reactions of a-oxygen as well as the data on the kinetic isotope effect and Moessbauer spectroscopy show FeZSM-5 zeolite to be a successful biomimetic model.