Thermal Desorption from Discretely Heterogeneous Surfaces with Account for Diffusion Between Various Surface Regions Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1993, Том: 49, Номер: 2, Страницы: 251-259 Страниц : 9 DOI: 10.1007/BF02067689 | ||
Ключевые слова | Entropy; Physical Chemistry; Surface Region; Adsorbed Layer; Catalysis; Desorption; Thermal diffusion; Thermal effects | ||
Авторы |
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Организации |
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Реферат:
Calculations for a discretely heterogeneous surface consisting of patches s1 and s2 with different adsorption heats of particles, Aads have been made. The calculated data show that under equilibrium distribution of particles between s1 and s2 the desorption rate over route II: s1* Aads → s2* Aads → Agas considerably increases compared to the “direct” desorption over route I: s1* Aads → Agas. This effect is ascribed to the entropy variations of adsorbed layers on patches s1 and s2.
Библиографическая ссылка:
Savchenko V.I.
Thermal Desorption from Discretely Heterogeneous Surfaces with Account for Diffusion Between Various Surface Regions
Reaction Kinetics and Catalysis Letters. 1993. V.49. N2. P.251-259. DOI: 10.1007/BF02067689 WOS Scopus РИНЦ
Thermal Desorption from Discretely Heterogeneous Surfaces with Account for Diffusion Between Various Surface Regions
Reaction Kinetics and Catalysis Letters. 1993. V.49. N2. P.251-259. DOI: 10.1007/BF02067689 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 8 дек. 1992 г. |
Принята к публикации: | 26 янв. 1993 г. |
Опубликована в печати: | 1 июн. 1993 г. |
Идентификаторы БД:
Web of science | WOS:A1993LP76200004 |
Scopus | 2-s2.0-0027615055 |
РИНЦ | 31105432 |
Chemical Abstracts | 1993:634799 |
Chemical Abstracts (print) | 119:234799 |
OpenAlex | W2002047475 |
Цитирование в БД:
Пока нет цитирований