Ruthenium Complexes with Heteropoly Anion PW11O39 7- and Their Redox Properties Научная публикация
Журнал |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Вых. Данные | Год: 1993, Том: 42, Номер: 8, Страницы: 1294-1300 Страниц : 7 DOI: 10.1007/BF00699917 | ||
Ключевые слова | perchlorate, chlorate, activation, redox reactions, ruthenium, heteropoly complexes | ||
Авторы |
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Организации |
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Реферат:
A new heteropoly complex PW11RuIV and complexes of RuII, RuIII and RuV based thereon have been obtained. Using specrophotometry the states of RuIII and RuIV complexes in solution, the pH range of their stability, and the interaction of PW11RuIV with ClO4 −, SO4 2− , Cl− ions have been studied. A conclusion has been thus made that the ruthenium ion in such a complex is not incorporated in the heteropolyanion lattice, but is attached only to its external oxygen atoms. Kinetics of oxidation of PW11RuIV and PW11RuIII with potassium chlorate have been studied. The activation energy and pre-exponential factor have been found for the reaction. The possibility that ClO4 − and ClO3 − in aqueous solutions can be activated by PW11RuII with the former and by PW11RuIII and PW11RuIV with the latter has been demonstrated.
Библиографическая ссылка:
Detusheva L.G.
, Kuznetsova L.I.
, Likholobov V.A.
Ruthenium Complexes with Heteropoly Anion PW11O39 7- and Their Redox Properties
Russian Chemical Bulletin. 1993. V.42. N8. P.1294-1300. DOI: 10.1007/BF00699917 WOS Scopus РИНЦ
Ruthenium Complexes with Heteropoly Anion PW11O39 7- and Their Redox Properties
Russian Chemical Bulletin. 1993. V.42. N8. P.1294-1300. DOI: 10.1007/BF00699917 WOS Scopus РИНЦ
Оригинальная:
Детушева Л.Г.
, Кузнецова Л.И.
, Лихолобов В.А.
Комплексы рутения с гетерополианионом PW11O39 7- и их окислительно-восстановительные свойства
Известия Академии наук. Серия химическая. 1993. №8. С.1363-1369. РИНЦ
Комплексы рутения с гетерополианионом PW11O39 7- и их окислительно-восстановительные свойства
Известия Академии наук. Серия химическая. 1993. №8. С.1363-1369. РИНЦ
Даты:
Поступила в редакцию: | 31 мар. 1993 г. |
Опубликована в печати: | 1 авг. 1993 г. |
Идентификаторы БД:
Web of science | WOS:A1993NT25400003 |
Scopus | 2-s2.0-21344478151 |
РИНЦ | 31147556 |
OpenAlex | W1997208827 |