Specific Features of the Gas-Chromatographic Determination of the Reaction Products in the Catalytic Decomposition of Hydrogen Sulfide Научная публикация
Журнал |
Journal of Analytical Chemistry
ISSN: 1061-9348 , E-ISSN: 1608-3199 |
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Вых. Данные | Год: 2006, Том: 61, Номер: 4, Страницы: 334-337 Страниц : 4 DOI: 10.1134/S106193480604006X | ||||
Ключевые слова | Hydrogen; Chromatography; Sulfide; Thermal Conductivity; Argon | ||||
Авторы |
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Организации |
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Реферат:
Specific features of the determination of hydrogen sulfide in the presence of hydrogen were studied by gas chromatography with the use of a thermal conductivity detector and argon as the carrier gas. A chromatographic column with HayeSep A modified with 10 wt % H3PO4 was proposed for the simultaneous determination of both components. It was demonstrated that the elution curve of hydrogen sulfide in an argon atmosphere has a non-Gaussian shape because of the interaction of hydrogen sulfide with the tungsten filament of the sensing element of the catarometer. To eliminate this interaction, it was recommended that a gold-plated tungsten filament be used in the detector.
Библиографическая ссылка:
Zheivot V.I.
, Krivoruchko V.N.
, Medvedev A.S.
, Voroshina O.V.
Specific Features of the Gas-Chromatographic Determination of the Reaction Products in the Catalytic Decomposition of Hydrogen Sulfide
Journal of Analytical Chemistry. 2006. V.61. N4. P.334-337. DOI: 10.1134/S106193480604006X WOS Scopus РИНЦ
Specific Features of the Gas-Chromatographic Determination of the Reaction Products in the Catalytic Decomposition of Hydrogen Sulfide
Journal of Analytical Chemistry. 2006. V.61. N4. P.334-337. DOI: 10.1134/S106193480604006X WOS Scopus РИНЦ
Оригинальная:
Жейвот В.И.
, Криворучко В.Н.
, Медведев А.С.
, Ворошина О.В.
Особенности газохроматографического определения продуктов реакции каталитического разложения сероводорода
Журнал аналитической химии. 2006. Т.61. №4. С.365-369. RSCI РИНЦ
Особенности газохроматографического определения продуктов реакции каталитического разложения сероводорода
Журнал аналитической химии. 2006. Т.61. №4. С.365-369. RSCI РИНЦ
Даты:
Поступила в редакцию: | 9 дек. 2004 г. |
Принята к публикации: | 25 апр. 2005 г. |
Опубликована в печати: | 1 апр. 2006 г. |
Идентификаторы БД:
Web of science | WOS:000236441000006 |
Scopus | 2-s2.0-33645501142 |
РИНЦ | 13518769 |
Chemical Abstracts | 2006:300638 |
Chemical Abstracts (print) | 145:39511 |
OpenAlex | W1984363045 |