Kinetics of Electrochemical Reactions on Model Supported Catalysts: Readsorption and Mass Transport Научная публикация
Журнал |
Surface Review and Letters
ISSN: 0218-625X , E-ISSN: 1793-6667 |
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Вых. Данные | Год: 2008, Том: 15, Номер: 6, Страницы: 745-751 Страниц : 7 DOI: 10.1142/S0218625X08011962 | ||||
Ключевые слова | Diffusion length, Electrochemical reactions, Intermediate desorption and readsorption, Laminar-flow conditions, Mass transport, Nm-sized supported catalyst particles, Reaction diffusion equations | ||||
Авторы |
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Организации |
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Реферат:
To bridge the structure gap, electrochemical reactions can be studied in flow cells with nm-sized catalyst particles deposited or fabricated on the cell walls. The understanding of the role of mass transport in such cells is now limited. To clarify the likely effects in this field, we analyze the simplest reaction scheme including intermediate desorption, readsorption, and subsequent reaction and show how the net rate of the formation of intermediate can be influenced by its diffusion in the liquid phase. With certain approximations, we derive analytical results describing reaction and diffusion near catalyst particles and in more remote regions in the simplest 1D case and more complex 2D and 3D situations.
Библиографическая ссылка:
Zhdanov V.P.
, Kasemo B.H.
Kinetics of Electrochemical Reactions on Model Supported Catalysts: Readsorption and Mass Transport
Surface Review and Letters. 2008. V.15. N6. P.745-751. DOI: 10.1142/S0218625X08011962 WOS Scopus РИНЦ
Kinetics of Electrochemical Reactions on Model Supported Catalysts: Readsorption and Mass Transport
Surface Review and Letters. 2008. V.15. N6. P.745-751. DOI: 10.1142/S0218625X08011962 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 15 июн. 2008 г. |
Опубликована в печати: | 1 дек. 2008 г. |
Опубликована online: | 25 янв. 2012 г. |
Идентификаторы БД:
Web of science | WOS:000262617800004 |
Scopus | 2-s2.0-58449122737 |
РИНЦ | 13584634 |
Chemical Abstracts | 2009:39424 |
Chemical Abstracts (print) | 151:480502 |
OpenAlex | W1993887651 |
Цитирование в БД:
Пока нет цитирований