Calculation of the E.S.R. Spectrum of a Dynamic Biradical System with More than Two Conformations Научная публикация
Журнал |
Molecular Physics
ISSN: 0026-8976 , E-ISSN: 1362-3028 |
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Вых. Данные | Год: 1976, Том: 32, Номер: 3, Страницы: 613-619 Страниц : 7 DOI: 10.1080/00268977600102081 | ||
Авторы |
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Организации |
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Реферат:
The E.S.R. spectrum of a biradical with any number of conformations is calculated. It is shown that in some cases the interpretation of the E.S.R. spectra of such biradicals can be carried out in terms of groups of the conformations with fast exchange inside the groups. It is shown also that in the case of fast exchange the averaging of describing spectrum parameters is performed over concentrations of the exchanging conformations but not over their lifetimes, as it was suggested earlier. A detailed treatment of the spectra of biradicals with three conformations is carried out, and the possibilities of the analysis of experimental spectra of long-chain nitroxide biradicals are shown.
Библиографическая ссылка:
Parmon V.N.
, Zhidomirov G.M.
Calculation of the E.S.R. Spectrum of a Dynamic Biradical System with More than Two Conformations
Molecular Physics. 1976. V.32. N3. P.613-619. DOI: 10.1080/00268977600102081 WOS Scopus РИНЦ
Calculation of the E.S.R. Spectrum of a Dynamic Biradical System with More than Two Conformations
Molecular Physics. 1976. V.32. N3. P.613-619. DOI: 10.1080/00268977600102081 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 5 янв. 1976 г. |
Принята к публикации: | 24 мар. 1976 г. |
Опубликована в печати: | 1 сент. 1976 г. |
Опубликована online: | 23 авг. 2006 г. |
Идентификаторы БД:
Web of science | WOS:A1976CG55300002 |
Scopus | 2-s2.0-1642380796 |
РИНЦ | 31110578 |
Chemical Abstracts | 1977:71577 |
Chemical Abstracts (print) | 86:71577 |
OpenAlex | W2039986660 |