Effect of Citric Acid and Triethylene Glycol Addition on the Reactivation of CoMo/γ-Al2O3 Hydrotreating Catalysts
Научная публикация
| Общая информация |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Конференция |
III Scientific-Technological Symposium "Catalytic Hydroprocessing in Oil Refining"
16-20 апр. 2018
,
Lyon, France
|
| Журнал |
Catalysis Today
ISSN: 0920-5861
, E-ISSN: 1873-4308
|
| Вых. Данные |
Год: 2019,
Том: 329,
Страницы: 35-43
Страниц
: 9
DOI:
10.1016/j.cattod.2018.10.017
|
| Ключевые слова |
Calcination Citric acid Cobalt compounds Fourier transform infrared spectroscopy Glycols Molybdenum compounds Sulfur compounds |
| Авторы |
Budukva S.V.
1
,
Klimov O.V.
1
,
Uvarkina D.D.
1
,
Chesalov Yu.A.
1
,
Prosvirin I.P.
1
,
Larina T.V.
1
,
Noskov A.S.
1
|
| Организации |
| 1 |
Boreskov Institute of Catalysis SB RAS, 5, pr. Lavrentieva, 630090 Novosibirsk, Russia
|
|
Информация о финансировании (1)
|
1
|
Федеральное агентство научных организаций России
|
0303-2016-0010
|
Calcined CoMo/γ-Al2O3 hydrotreating catalysts were reactivated by a solution of citric acid and triethylene glycol. The reactivated catalysts were tested in HDS of dibenzothiophene and hydrotreating of SRGO. The reactivated catalysts were showed a significant increase in activity compared to calcined. The highest reactivation was observed for the sample reactivated using a solution of citric acid and triethylene glycol. All catalysts were characterized by means of UV-DRS, FTIR, Raman spectroscopy, XRD, XPS, and HTREM. It has been shown that the addition of triethylene glycol increases the proportion of CoMoS phase and the dispersion of sulfide particles.