Reactivity of α-Pinene Epoxide in Supercritical Solvents Научная публикация
Журнал |
The Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162 |
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Вых. Данные | Год: 2010, Том: 52, Номер: 1, Страницы: 71-75 Страниц : 5 DOI: 10.1016/j.supflu.2009.11.003 | ||||
Ключевые слова | Supercritical carbon dioxide and low alcohols, Transformation of α-pinene epoxide | ||||
Авторы |
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Организации |
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Реферат:
Thermal transformations of α-pinene epoxide in composite supercritical solvents that contain CO2, lower alcohols (ethanol, isopropyl alcohol) and water were studied in the temperature range of 387–575 K at pressure 13.5–21.5 MPa. Campholenic aldehyde and carveol were shown to be the main products of α-pinene epoxide reactions in supercritical solvents containing water. In the absence of water, thermolysis of α-pinene epoxide in supercritical solvent yields campholenic aldehyde and pinocamphone, with their total amount in the reaction mixture attaining 80%. Suggestions were made on the mechanism of α-pinene epoxide thermal isomerization depending on acidity of supercritical solvent.
Библиографическая ссылка:
Anikeev V.I.
, Ilʹina I.V.
, Volcho K.P.
, Ermakova A.
, Salakhutdinov N.F.
Reactivity of α-Pinene Epoxide in Supercritical Solvents
The Journal of Supercritical Fluids. 2010. V.52. N1. P.71-75. DOI: 10.1016/j.supflu.2009.11.003 WOS Scopus РИНЦ
Reactivity of α-Pinene Epoxide in Supercritical Solvents
The Journal of Supercritical Fluids. 2010. V.52. N1. P.71-75. DOI: 10.1016/j.supflu.2009.11.003 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 7 июл. 2009 г. |
Принята к публикации: | 12 нояб. 2009 г. |
Опубликована online: | 18 нояб. 2009 г. |
Опубликована в печати: | 1 февр. 2010 г. |
Идентификаторы БД:
Web of science | WOS:000274932100010 |
Scopus | 2-s2.0-74449089103 |
РИНЦ | 15325868 |
Chemical Abstracts | 2010:103298 |
Chemical Abstracts (print) | 152:454274 |
OpenAlex | W2130435594 |