Green Stereoselective Oxidations, Catalyzed by Bioinspired bis-Amine-bis-Pyridine Manganese Complexes Тезисы доклада
Конференция |
7th Asian Conference on Coordination Chemistry 15-18 окт. 2019 , Kuala Lumpur |
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Сборник | 7th Asian Conference on Coordination Chemistry.Abstract Book Сборник, 2019. 340 c. |
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Вых. Данные | Год: 2019, Страницы: 26 Страниц : 1 | ||||
Ключевые слова | asymmetric; epoxidation; C-H oxidation; manganese; hydrogen peroxide | ||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Российский фонд фундаментальных исследований | 16-29-10666 |
Реферат:
In recent years, great efforts have been invested into the design of bioinspired manganese complexes, capable of conducting chemo- and stereoselective oxidations of complex organic molecules,1 such as asymmetric epoxidations, stereoselective and stereospecific C-H oxidations, oxidative desymmetrization of cyclic substrates, kinetic resolution of secondary alcohols, etc.2 In this contribution, we present an overview of the versatile catalytic reactivity of chiral bisamine-bis-pyridine manganese complexes, developed in our group and eslewhere, in a variety of asymmetric oxygenations with the environmentally benign oxidant hydrogen peroxide. Current understanding of the nature of the catalytically active, presumably high-valent manganese-oxo species, is presented.
Библиографическая ссылка:
Ottenbacher R.V.
, Bryliakova A.A.
, Talsi E.P.
, Bryliakov K.P.
Green Stereoselective Oxidations, Catalyzed by Bioinspired bis-Amine-bis-Pyridine Manganese Complexes
В сборнике 7th Asian Conference on Coordination Chemistry.Abstract Book. 2019. – C.26.
Green Stereoselective Oxidations, Catalyzed by Bioinspired bis-Amine-bis-Pyridine Manganese Complexes
В сборнике 7th Asian Conference on Coordination Chemistry.Abstract Book. 2019. – C.26.
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