Platinum Acetate Blue: Synthesis and Characterization
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Inorganic Chemistry
ISSN: 0020-1669
, E-ISSN: 1520-510X
|
| Вых. Данные |
Год: 2014,
Том: 53,
Номер: 16,
Страницы: 8397-8406
Страниц
: 10
DOI:
10.1021/ic500940a
|
| Авторы |
Cherkashina Natalia V.
1
,
Kochubey Dmitry I.
1
,
Kanazhevskiy Vladislav V.
1
,
Zaikovskii Vladimir I.
2,3
,
Ivanov Vladimir K.
1
,
Markov Alexander A.
1
,
Klyagina Alla P.
1
,
Dobrokhotova Zhanna V.
1
,
Kozitsyna Natalia Yu.
1
,
Baranovsky Igor B.
1
,
Ellert Olga G.
1
,
Efimov Nikolai N.
1
,
Nefedov Sergei E.
1
,
Novotortsev Vladimir M.
1
,
Vargaftik Michael N.
1
,
Moiseev Ilya I.
1
|
| Организации |
| 1 |
N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russian Federation
|
| 2 |
G.K. Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, 630090, Novosibirsk, Russian Federation
|
| 3 |
Novosibirsk State University, 630090, Novosibirsk, Russian Federation
|
|
Информация о финансировании (4)
|
1
|
Российский фонд фундаментальных исследований
|
12-03-00917
|
|
2
|
Российский фонд фундаментальных исследований
|
12-03-31325
|
|
3
|
Совет по грантам Президента Российской Федерации
|
НШ-1712.2014.3
|
|
4
|
Президиум РАН
|
|
Platinum acetate blue (PAB) of the empirical formula Pt(OOCMe)2.5±0.25, a byproduct in the synthesis of crystalline platinum(II) acetate Pt4(OOCMe)8, is an X-ray amorphous substance containing platinum in the oxidation state between (II) and (III). Typical PAB samples were studied with X-ray diffraction, differential thermal analysis-thermogravimetric, extended X-ray absorption fine structure, scanning electron microscopy, transmission electron microscopy, magnetochemistry, and combined quantum chemical density functional theory-molecular mechanics modeling to reveal the main structural features of the PAB molecular building blocks. The applicability of PAB to the synthesis of platinum complexes was demonstrated by the preparation of the new homo- and heteronuclear complexes Pt(II)(dipy)(OOCMe)2 (1), Pt(II)(μ-OOCMe)4Co(II)(OH2) (2), and Pt(III)2(OOCMe)4(O3SPhMe)2 (3) with the use of PAB as starting material.