Raman Spectra for Characterization of Defective CVD Multi-Walled Carbon Nanotubes
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Physica Status Solidi (B): Basic Research
ISSN: 0370-1972
, E-ISSN: 1521-3951
|
| Вых. Данные |
Год: 2014,
Том: 251,
Номер: 12,
Страницы: 2444-2450
Страниц
: 7
DOI:
10.1002/pssb.201451195
|
| Ключевые слова |
Bimetallic catalysts, Graphene flakes, Multi-walled carbon nanotubes, Raman spectroscopy |
| Авторы |
Kuznetsov Vladimir L.
1,2,5
,
Bokova-Sirosh Sofya N.
3,6
,
Moseenkov Sergey I.
1
,
Ishchenko Arcady V.
1,2
,
Krasnikov Dmitry V.
1,2
,
Kazakova Mariya A.
1,2
,
Romanenko Anatoly I.
4
,
Tkachev Evgeniy N.
4
,
Obraztsova Elena D.
3,6
|
| Организации |
| 1 |
Boreskov Institute of Catalysis SB RAS, Lavrentieva ave. 5, Novosibirsk 630090, Russia
|
| 2 |
Novosibirsk State University, Pirogova str. 2, Novosibirsk 630090, Russia
|
| 3 |
A. M. Prokhorov General Physics Institute, RAS, 38 Vavilova str., Moscow 119991, Russia
|
| 4 |
Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentieva ave. 3, Novosibirsk 630090, Russia
|
| 5 |
National Tomsk State University, Lenina ave. 36, Tomsk 634050, Russia
|
| 6 |
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Kashirskoye shosse 31, Moscow 115409, Russia
|
|
Информация о финансировании (5)
|
1
|
Министерство образования и науки Российской Федерации
|
14.607.21.0046 (RFMEFI60714X0046)
|
|
2
|
Российский фонд фундаментальных исследований
|
14-03-31355
|
|
3
|
Президиум РАН
|
24
|
|
4
|
Российский фонд фундаментальных исследований
|
13-02-01354
|
|
5
|
Совет по грантам Президента Российской Федерации
|
СП-1540.2012.3
|
Curved graphene fragments can be considered as building blocks of carbon nanotubes. Thus, the size of graphene fragments may be considered as one of the most important characteristics of their structural disorder. In this paper, we have performed a comparative Raman study of CVD multi-walled carbon nanotubes (MWCNTs) and graphene flakes deposited on MWCNTs. Raman data have been considered in combination with HRTEM characterization of nanotubes. The basic attention has been paid to the behavior of D (disorder-induced), G (tangential mode), and
2D (two-phonon scattering) bands in Raman spectra in order to use them for MWCNT characterization. A ratio of intensities of 2D and D bands (I2D/ID) demonstrates almost a linear dependence on the mean diameter of MWCNTs produced with two different types of catalysts (see abstract figure). It should be mentioned that each type of catalyst provides the linear dependence with its own specific slope. The graphene fragments have been proposed to form a mosaic structure of nanotube walls. I2D/ID ratio depends on the amount of graphene flakes deposited on nanotube surface via ethylene decomposition. A dependence of intensity ratio I2D/ID on the diameter of nanotubes produced with different types of catalysts.