Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation Научная публикация
Конференция |
Catalysis for sustainable development : Russian-Dutch Workshop 22-26 июн. 2002 , Novosibirsk, Russia |
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Журнал |
Chemistry for Sustainable Development
ISSN: 1817-1818 |
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Вых. Данные | Год: 2003, Том: 11, Номер: 1, Страницы: 123-130 Страниц : 8 | ||||||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Российский фонд фундаментальных исследований | 00-03-32407 |
Реферат:
Relationship of structure and surface properties of modified titanium dioxides, prepared by alkoxide method using derivatives of phosphoric acid as precursors, with their catalytic performance in the reaction of ethylene glycol ethoxylation was investigated. It was found, that such catalysts are mono-phase, nanocluster ones with anatase structure, and have uniform narrow pore distribution. Catalysts prepared using the amidophosphite precursors provide high catalytic activity due to the high surface acidity, and high selectivity of diethylene glycol formation due to the "sieve effect" and concert acid-base mechanism of ethylene oxide addition.
Paper
Библиографическая ссылка:
Kozlovskiy R.A.
, Shvets V.F.
, Kustov A.V.
, Kitaev L.E.
, Yuschenko V.V.
, Kriventsov V.V.
, Kochubey D.I.
, Tsodikov M.V.
Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation
Chemistry for Sustainable Development. 2003. V.11. N1. P.123-130. РИНЦ
Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation
Chemistry for Sustainable Development. 2003. V.11. N1. P.123-130. РИНЦ
Оригинальная:
Kozlovskiy R.A.
, Shvets V.F.
, Koustov A.V.
, Kitaev L.E.
, Yushchenko V.V.
, Kriventsov V.V.
, Kochubey D.I.
, Tsodikov M.V.
Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation
Химия в интересах устойчивого развития. 2003. V.11. N1. P.123-130. РИНЦ
Relationship between Surface Properties of Modified Titanooxides and Their Catalytic Performance in the Reaction of Ethylene Glycol Ethoxylation
Химия в интересах устойчивого развития. 2003. V.11. N1. P.123-130. РИНЦ
Идентификаторы БД:
РИНЦ | 30656832 |
Цитирование в БД:
Пока нет цитирований