Compounds Featuring the Structural Fragment P-C-P Full article
Journal |
Phosphorus, Sulfur, and Silicon and the Related Elements (1989-current)
ISSN: 1563-5325 , E-ISSN: 1042-6507 |
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Output data | Year: 2011, Volume: 186, Pages: 621-625 Pages count : 5 DOI: 10.1080/10426507.2010.520285 | ||||||||||
Tags | Azaphospholes, Diphosphiranes, Hypervalency, Phosphanes, Ylides, Zwitterions | ||||||||||
Authors |
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Affiliations |
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Funding (4)
1 | German Research Foundation | |
2 | Alexander von Humboldt Foundation | |
3 | Swiss National Science Foundation | |
4 | National Academy of Sciences of Ukraine |
Abstract:
This article summarizes some of our investigations of compounds featuring the structural fragment P‒C‒P. Phosphorus atoms in different oxidation states and coordination numbers display different chemical behaviors. This may lead to unique chemical properties when they are bridged by a methylene group in a P‒CH2‒P system. For example, the PIII‒CH2‒PVunit is able to add different unsaturated compounds to give zwitterionic products with oppositely charged phosphorus atoms. In addition, the two hydrogen atoms in P‒CH2‒P may also take part in different transformations, resulting in the formation of carbodiphosphoranes or in the formation of a direct P-P bond to give three-membered ring diphosphiranes.
Cite:
Shevchenko I.
, Tarasevych A.
, Turcheniuk K.
, Mikolenko R.
, Andrushko V.
, Rozhenko A.
, Schmutzler R.
, Grützmacher H.
, Röschenthaler G.-V.
Compounds Featuring the Structural Fragment P-C-P
Phosphorus, Sulfur, and Silicon and the Related Elements (1989-current). 2011. V.186. P.621-625. DOI: 10.1080/10426507.2010.520285 WOS Scopus РИНЦ
Compounds Featuring the Structural Fragment P-C-P
Phosphorus, Sulfur, and Silicon and the Related Elements (1989-current). 2011. V.186. P.621-625. DOI: 10.1080/10426507.2010.520285 WOS Scopus РИНЦ
Dates:
Submitted: | Jul 5, 2010 |
Accepted: | Aug 30, 2010 |
Published print: | Mar 31, 2011 |
Published online: | Apr 25, 2011 |
Identifiers:
Web of science | WOS:000290046600002 |
Scopus | 2-s2.0-79955757364 |
Elibrary | 27802668 |
Chemical Abstracts | 2011:520760 |
Chemical Abstracts (print) | 155:12024 |
OpenAlex | W2024291344 |