Catalysts Based on Fiberglass Supports: V. Absorption and Catalytic Properties of Palladium Catalysts Based on a Leached Silica-Fiberglass Support in the Selective Hydrogenation of an Ethylene-Acetylene Mixture | Sciact - CRIS-система Института катализа

Catalysts Based on Fiberglass Supports: V. Absorption and Catalytic Properties of Palladium Catalysts Based on a Leached Silica-Fiberglass Support in the Selective Hydrogenation of an Ethylene-Acetylene Mixture Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2002, Том: 43, Номер: 4, Страницы: 542-549 Страниц : 8 DOI: 10.1023/A:1019835303914

Ключевые слова

Hydrogenation; Soda; Ethylene; Physical Chemistry; Catalysis

Авторы

Balʹzhinimaev B.S. ¹ , Barelko V.V. ² , Suknev A.P. ¹ , Paukshtis E.A. ¹ , Simonova L.G. ¹ , Goncharov V.B. ¹ , Kirillov V.L. ¹ , Toktarev A.V. ¹

Организации

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432 Russia

The absorption and catalytic properties of palladium catalysts (0.01% Pd) based on leached soda–silica fiberglass supports were studied in the selective hydrogenation of acetylene as the constituent of an ethylene–acetylene mixture. It was found that fiberglass catalysts exhibited much higher selectivity than traditional supported Pd catalysts. It was suggested that the high selectivity in the reaction of acetylene hydrogenation resulted from the selective absorption (diffusion) of acetylene in the bulk of fiberglass, where Pd microparticles are localized.

Balʹzhinimaev B.S. , Barelko V.V. , Suknev A.P. , Paukshtis E.A. , Simonova L.G. , Goncharov V.B. , Kirillov V.L. , Toktarev A.V.
Catalysts Based on Fiberglass Supports: V. Absorption and Catalytic Properties of Palladium Catalysts Based on a Leached Silica-Fiberglass Support in the Selective Hydrogenation of an Ethylene-Acetylene Mixture
Kinetics and Catalysis. 2002. V.43. N4. P.542-549. DOI: 10.1023/A:1019835303914 WOS Scopus РИНЦ CAPlusCA OpenAlex

Бальжинимаев Б.С. , Барелко В.В. , Сукнев А.П. , Паукштис Е.А. , Симонова Л.Г. , Гончаров В.Б. , Кириллов В.Л. , Токтарев А.В.
Катализаторы на основе стекловолокнистых носителей. V. Абсорбционные и каталитические свойства Pd-катализаторов на основе выщелоченного кремнеземного стекловолокнистого носителя в реакции селективного гидрирования этилен-ацетиленовой смеси
Кинетика и катализ. 2002. Т.43. №4. С.586-594. РИНЦ

Поступила в редакцию:	22 авг. 2001 г.
Опубликована в печати:	1 июл. 2002 г.

Web of science:	WOS:000177849400014
Scopus:	2-s2.0-0038237963
РИНЦ:	13394638
Chemical Abstracts:	2002:627511
Chemical Abstracts (print):	137:370375
OpenAlex:	W153664098

БД	Цитирований
Web of science	14
Scopus	27
РИНЦ	33
OpenAlex	26