Catalysts Based on Fiberglass Supports: V. Absorption and Catalytic Properties of Palladium Catalysts Based on a Leached Silica-Fiberglass Support in the Selective Hydrogenation of an Ethylene-Acetylene Mixture Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2002, Volume: 43, Number: 4, Pages: 542-549 Pages count : 8 DOI: 10.1023/A:1019835303914 | ||||
| Tags | Hydrogenation; Soda; Ethylene; Physical Chemistry; Catalysis | ||||
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Abstract:
The absorption and catalytic properties of palladium catalysts (0.01% Pd) based on leached soda–silica fiberglass supports were studied in the selective hydrogenation of acetylene as the constituent of an ethylene–acetylene mixture. It was found that fiberglass catalysts exhibited much higher selectivity than traditional supported Pd catalysts. It was suggested that the high selectivity in the reaction of acetylene hydrogenation resulted from the selective absorption (diffusion) of acetylene in the bulk of fiberglass, where Pd microparticles are localized.
Cite:
Balʹzhinimaev B.S.
, Barelko V.V.
, Suknev A.P.
, Paukshtis E.A.
, Simonova L.G.
, Goncharov V.B.
, Kirillov V.L.
, Toktarev A.V.
Catalysts Based on Fiberglass Supports: V. Absorption and Catalytic Properties of Palladium Catalysts Based on a Leached Silica-Fiberglass Support in the Selective Hydrogenation of an Ethylene-Acetylene Mixture
Kinetics and Catalysis. 2002. V.43. N4. P.542-549. DOI: 10.1023/A:1019835303914 WOS Scopus РИНЦ OpenAlex ANCAN
Catalysts Based on Fiberglass Supports: V. Absorption and Catalytic Properties of Palladium Catalysts Based on a Leached Silica-Fiberglass Support in the Selective Hydrogenation of an Ethylene-Acetylene Mixture
Kinetics and Catalysis. 2002. V.43. N4. P.542-549. DOI: 10.1023/A:1019835303914 WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Бальжинимаев Б.С.
, Барелко В.В.
, Сукнев А.П.
, Паукштис Е.А.
, Симонова Л.Г.
, Гончаров В.Б.
, Кириллов В.Л.
, Токтарев А.В.
Катализаторы на основе стекловолокнистых носителей. V. Абсорбционные и каталитические свойства Pd-катализаторов на основе выщелоченного кремнеземного стекловолокнистого носителя в реакции селективного гидрирования этилен-ацетиленовой смеси
Кинетика и катализ. 2002. Т.43. №4. С.586-594. РИНЦ
Катализаторы на основе стекловолокнистых носителей. V. Абсорбционные и каталитические свойства Pd-катализаторов на основе выщелоченного кремнеземного стекловолокнистого носителя в реакции селективного гидрирования этилен-ацетиленовой смеси
Кинетика и катализ. 2002. Т.43. №4. С.586-594. РИНЦ
Dates:
| Submitted: | Aug 22, 2001 |
| Published print: | Jul 1, 2002 |
Identifiers:
| ≡ Web of science: | WOS:000177849400014 |
| ≡ Scopus: | 2-s2.0-0038237963 |
| ≡ Elibrary: | 13394638 |
| ≡ OpenAlex: | W153664098 |
| ≡ Chemical Abstracts: | 2002:627511 |
| ≡ Chemical Abstracts (print): | 137:370375 |