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Cyclohexanone Preparation via the Gas Phase Carboxidation of Cyclohexene by Nitrous Oxide Научная публикация

Журнал Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Вых. Данные Год: 2005, Том: 84, Номер: 2, Страницы: 383-388 Страниц : 6 DOI: 10.1007/s11144-005-0233-2
Ключевые слова Carbonyl compounds, Cyclohexanone, Cyclohexene, Nitrous oxide, Oxidation
Авторы Starokon E.V. 1 , Dubkov K.A. 1 , Parmon V.N. 1 , Panov G.I. 1
Организации
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russia

Реферат: Nitrous oxide is known to provide non-catalytic liquid phase oxidation of alkenes to carbonyl compounds (the carboxidation reaction). This paper shows that carboxidation of cyclohexene can be successfully conducted in the gas phase, too. The gas phase carboxidation is a second order reaction proceeding at 325-450oC under 3-16 bar pressure with an activation energy of 26 kcal/mol. The reaction mechanism does not involve free radical steps and leads to cyclohexanone as a main product.
Библиографическая ссылка: Starokon E.V. , Dubkov K.A. , Parmon V.N. , Panov G.I.
Cyclohexanone Preparation via the Gas Phase Carboxidation of Cyclohexene by Nitrous Oxide
Reaction Kinetics and Catalysis Letters. 2005. V.84. N2. P.383-388. DOI: 10.1007/s11144-005-0233-2 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 17 дек. 2004 г.
Принята к публикации: 23 дек. 2004 г.
Опубликована в печати: 1 мар. 2005 г.
Идентификаторы БД:
Web of science: WOS:000229264300023
Scopus: 2-s2.0-17444418328
РИНЦ: 13474708
Chemical Abstracts: 2005:293708
Chemical Abstracts (print): 142:446851
OpenAlex: W2321023129
Цитирование в БД:
БД Цитирований
Web of science 12
Scopus 11
РИНЦ 13
OpenAlex 10
Альметрики: