Cyclohexanone Preparation via the Gas Phase Carboxidation of Cyclohexene by Nitrous Oxide Full article
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Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 2005, Volume: 84, Number: 2, Pages: 383-388 Pages count : 6 DOI: 10.1007/s11144-005-0233-2 | ||
| Tags | Carbonyl compounds, Cyclohexanone, Cyclohexene, Nitrous oxide, Oxidation | ||
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Abstract:
Nitrous oxide is known to provide non-catalytic liquid phase oxidation of alkenes to carbonyl compounds (the carboxidation reaction). This paper shows that carboxidation of cyclohexene can be successfully conducted in the gas phase, too. The gas phase carboxidation is a second order reaction proceeding at 325-450oC under 3-16 bar pressure with an activation energy of 26 kcal/mol. The reaction mechanism does not involve free radical steps and leads to cyclohexanone as a main product.
Cite:
Starokon E.V.
, Dubkov K.A.
, Parmon V.N.
, Panov G.I.
Cyclohexanone Preparation via the Gas Phase Carboxidation of Cyclohexene by Nitrous Oxide
Reaction Kinetics and Catalysis Letters. 2005. V.84. N2. P.383-388. DOI: 10.1007/s11144-005-0233-2 WOS Scopus РИНЦ ANCAN OpenAlex
Cyclohexanone Preparation via the Gas Phase Carboxidation of Cyclohexene by Nitrous Oxide
Reaction Kinetics and Catalysis Letters. 2005. V.84. N2. P.383-388. DOI: 10.1007/s11144-005-0233-2 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Dec 17, 2004 |
| Accepted: | Dec 23, 2004 |
| Published print: | Mar 1, 2005 |
Identifiers:
| Web of science: | WOS:000229264300023 |
| Scopus: | 2-s2.0-17444418328 |
| Elibrary: | 13474708 |
| Chemical Abstracts: | 2005:293708 |
| Chemical Abstracts (print): | 142:446851 |
| OpenAlex: | W2321023129 |