Methanol Synthesis on Palladium Nanoparticles: Size Effect Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 1996, Том: 59, Номер: 2, Страницы: 351-357 Страниц : 7 DOI: 10.1007/BF02068133 | ||
| Ключевые слова | Methanol synthesis, Pd/SiO2, Size effect | ||
| Авторы |
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| Организации |
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Реферат:
The turnover number (TON) of Pd/SiO2 in methanol synthesis increases by one order of magnitude with the growth of Pd particle size from 10 to 30 Å. Further particle size increase to 60 Å does not alter the TON. The fraction of bridged adsorbed CO decreases with the growth of Pd dispersion. Low TON of Pd nanoparticles is caused by the decrease of CO chemisorption strength on small electron-deficient Pd particles.
Библиографическая ссылка:
Kirillov V.L.
, Ryndin Y.A.
Methanol Synthesis on Palladium Nanoparticles: Size Effect
Reaction Kinetics and Catalysis Letters. 1996. V.59. N2. P.351-357. DOI: 10.1007/BF02068133 WOS Scopus РИНЦ CAPlusCA OpenAlex
Methanol Synthesis on Palladium Nanoparticles: Size Effect
Reaction Kinetics and Catalysis Letters. 1996. V.59. N2. P.351-357. DOI: 10.1007/BF02068133 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 15 мар. 1996 г. |
| Принята к публикации: | 12 июн. 1996 г. |
| Опубликована в печати: | 1 нояб. 1996 г. |
Идентификаторы БД:
| Web of science: | WOS:A1996WN65600022 |
| Scopus: | 2-s2.0-0000232934 |
| РИНЦ: | 13231698 |
| Chemical Abstracts: | 1997:150493 |
| Chemical Abstracts (print): | 126:224995 |
| OpenAlex: | W2018132777 |