Methanol Synthesis on Palladium Nanoparticles: Size Effect Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 1996, Volume: 59, Number: 2, Pages: 351-357 Pages count : 7 DOI: 10.1007/BF02068133 | ||
| Tags | Methanol synthesis, Pd/SiO2, Size effect | ||
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| Affiliations |
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Abstract:
The turnover number (TON) of Pd/SiO2 in methanol synthesis increases by one order of magnitude with the growth of Pd particle size from 10 to 30 Å. Further particle size increase to 60 Å does not alter the TON. The fraction of bridged adsorbed CO decreases with the growth of Pd dispersion. Low TON of Pd nanoparticles is caused by the decrease of CO chemisorption strength on small electron-deficient Pd particles.
Cite:
Kirillov V.L.
, Ryndin Y.A.
Methanol Synthesis on Palladium Nanoparticles: Size Effect
Reaction Kinetics and Catalysis Letters. 1996. V.59. N2. P.351-357. DOI: 10.1007/BF02068133 WOS Scopus РИНЦ OpenAlex ANCAN
Methanol Synthesis on Palladium Nanoparticles: Size Effect
Reaction Kinetics and Catalysis Letters. 1996. V.59. N2. P.351-357. DOI: 10.1007/BF02068133 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Mar 15, 1996 |
| Accepted: | Jun 12, 1996 |
| Published print: | Nov 1, 1996 |
Identifiers:
| ≡ Web of science: | WOS:A1996WN65600022 |
| ≡ Scopus: | 2-s2.0-0000232934 |
| ≡ Elibrary: | 13231698 |
| ≡ OpenAlex: | W2018132777 |
| ≡ Chemical Abstracts: | 1997:150493 |
| ≡ Chemical Abstracts (print): | 126:224995 |