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Iron Complexes in Zeolites as a New Model of Methane Monooxygenase Научная публикация

Журнал Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Вых. Данные Год: 1997, Том: 61, Номер: 2, Страницы: 251-258 Страниц : 8 DOI: 10.1007/BF02478380
Ключевые слова Iron complexes, Kinetic isotope effect, Methane oxidation, Methanol, Mössbauer spectroscopy, Nitrous oxide, ZSM-5 zeolite
Авторы Panov G.I. 1 , Sobolev V.I. 1 , Dubkov K.A. 1 , Parmon V.N. 1 , Ovanesyan N.S. 2 , Shilov A.E. 2 , Shteinman A.A. 2
Организации
1 Federal Scientific Center, Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
2 Institute of Chemical Physics in Chernogolovka, Moscow Region, Chemogolovka 142432, Russia

Информация о финансировании (5)

1 International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union 93-315
2 International Science Foundation REU 300
3 International Science Foundation JBD 100
4 Российский фонд фундаментальных исследований 94-03-08529
5 Российский фонд фундаментальных исследований 96-03-32985

Реферат: Iron complexes in the ZSM-5 zeolite matrix (α-centers) are shown to perform single-turnover cycles of methane oxidation to methanol at room temperature when nitrous oxide is used as a source of oxygen. The origin of carbon and oxygen in the product methanol was traced using 13C and 18O isotopes. Probable structure of α-sites as well as mechanistic features of the reaction allow to consider this system as a first successful model of methane monooxygenase.
Библиографическая ссылка: Panov G.I. , Sobolev V.I. , Dubkov K.A. , Parmon V.N. , Ovanesyan N.S. , Shilov A.E. , Shteinman A.A.
Iron Complexes in Zeolites as a New Model of Methane Monooxygenase
Reaction Kinetics and Catalysis Letters. 1997. V.61. N2. P.251-258. DOI: 10.1007/BF02478380 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 14 нояб. 1996 г.
Принята к публикации: 3 февр. 1997 г.
Опубликована в печати: 1 июл. 1997 г.
Идентификаторы БД:
Web of science: WOS:A1997XN88600005
Scopus: 2-s2.0-0001293726
РИНЦ: 13271086
Chemical Abstracts: 1997:608352
Chemical Abstracts (print): 127:304664
OpenAlex: W2050009077
Цитирование в БД:
БД Цитирований
Web of science 146
Scopus 159
РИНЦ 154
OpenAlex 160
Альметрики: